Recent progress in Ru electrocatalyst design for acidic oxygen evolution reaction

被引：0

作者：

Cui, Yuteng ^{[1
]}

Zhao, Yan ^{[1
]}

Han, Zhenyong ^{[1
]}

Wang, Zeyu ^{[1
]}

Li, Wenjun ^{[1
]}

Zhang, Yining ^{[2
]}

Li, Zhijun ^{[1
]}

Wang, Wanglei ^{[1
]}

Fu, Xiaogang ^{[1
]}

机构：

[1] Northwestern Polytech Univ, Sch Mat Sci & Engn, State Key Lab Solidificat Proc, Atom Control & Catalysis Engn Lab, Xian 710072, Shaanxi, Peoples R China

[2] Yulin Innovat Inst Clean Energy, Yulin 719000, Shanxi, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2025年 / 13卷 / 23期

基金：

中国国家自然科学基金;

关键词：

METAL-OXIDES; WATER; REDUCTION; CATALYSTS; EFFICIENT; NANOPARTICLES; PERFORMANCE; NANOSHEETS; STABILITY; OXIDATION;

D O I：

10.1039/d5ta01849h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Proton Exchange Membrane Water Electrolysis (PEMWE) offers a sustainable approach to addressing global energy and environmental challenges by efficiently producing clean hydrogen from intermittent renewable energy sources. A primary limitation of PEMWE lies in the anodic oxygen evolution reaction (OER), which involves a slow four-electron transfer process. Ru-based catalysts play a crucial role in overcoming this kinetic barrier but suffer from insufficient acidic OER activity and long-term stability. This review first examines the fundamental mechanisms of acidic OER, emphasizing the reaction pathways and degradation processes specific to Ru-based catalysts. Building on these insights, we propose several strategies to enhance catalytic performance, including structural modifications, elemental doping, support material optimization, and regulation of the OER pathway. This review also assesses the real-world efficacy of Ru-based catalysts in practical electrolyzer systems. Finally, the unresolved challenges and potential research directions for advancing Ru-based OER catalysts for scalable hydrogen production are discussed.

引用

页码：17214 / 17241

页数：28

共 182 条

[1]

Ahmad M. H., 2021, ADV ENERGY MATER, V11

[2] Amorphous Catalysts and Electrochemical Water Splitting: An Untold Story of Harmony [J].

Anantharaj, Sengeni ;

Noda, Suguru .

SMALL, 2020, 16 (02)

[3] Low Ruthenium Content Confined on Boron Carbon Nitride as an Efficient and Stable Electrocatalyst for Acidic Oxygen Evolution Reaction [J].

Bai, Xiaofang ;

Zhang, Xiuping ;

Sun, Yujiao ;

Huang, Mingcheng ;

Fan, Jiantao ;

Xu, Shaoyi ;

Li, Hui .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (38)

[4] Synergistic Engineering of Dopant and Support of Ru Oxide Catalyst Enables Ultrahigh Performance for Acidic Oxygen Evolution [J].

Boakye, Felix Ofori ;

Harrath, Karim ;

Zhang, Dantong ;

You, Ya ;

Zhang, Wenbin ;

Wang, Zheng ;

Zhang, Haining ;

Zhu, Jiexin ;

Long, Juncai ;

Zhu, Jianqiu ;

Yasin, Ghulam ;

Owusu, Kwadwo Asare ;

Tabish, Mohammad ;

Zhang, Linjuan ;

Wang, Dingsheng ;

Shi, Xiaofeng ;

Jiang, Zhongyi ;

Wu, Bin ;

Mai, Liqiang ;

Zhao, Wei .

ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (48)

[5] Regulation of Oxide Pathway Mechanism for Sustainable Acidic Water Oxidation [J].

Cao, Xuejie ;

Qin, Hongye ;

Zhang, Jinyang ;

Chen, Xiaojie ;

Jiao, Lifang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (46) :32049-32058

[6] Oxygen Radical Coupling on Short-Range Ordered Ru Atom Arrays Enables Exceptional Activity and Stability for Acidic Water Oxidation [J].

Chang, Jiangwei ;

Shi, Yuanyuan ;

Wu, Han ;

Yu, Jingkun ;

Jing, Wen ;

Wang, Siyang ;

Waterhouse, Geoffrey I. N. ;

Tang, Zhiyong ;

Lu, Siyu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (19) :12958-12968

[7]

Chao L., 2021, NAT CATAL, V4, P1012

[8] A Long-Range Disordering RuO2 Catalyst for Highly Efficient Acidic Oxygen Evolution Electrocatalysis [J].

Chen, Guanzhen ;

Lu, Ruihu ;

Ma, Chao ;

Zhang, Xuewen ;

Wang, Ziyun ;

Xiong, Yu ;

Han, Yunhu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (50)

[9] Asymmetric Bond Delta-Polarization at the Interfacial Se―Ru―O Bridge for Efficient pH-Robust Water Electrolysis [J].

Chen, Ya ;

Liu, Yaoda ;

Li, Lei ;

Sakthive, Thangavel ;

Guo, Zhixin ;

Dai, Zhengfei .

ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (46)

[10] Sm-Induced Symmetry-Broken Ru Centers for Boosting Acidic Water Oxidation [J].

Chen, Yunfei ;

Li, Zijian ;

Jang, Haeseong ;

Wang, Zhe ;

Kim, Min Gyu ;

Qin, Qing ;

Liu, Xien .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (15) :5884-5892

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