Iron(I) and Iron(II) Boxmi Pincer Complexes: Coordination Chemistry and Catalytic Hydroboration of Nitriles

被引：0

作者：

Buergy, David ^{[1
]}

Blasius, Clemens K. ^{[1
]}

Bruckhoff, Tim ^{[1
]}

Maurmann, Jonas ^{[1
]}

Wadepohl, Hubert ^{[1
]}

Ballmann, Joachim ^{[1
]}

Gade, Lutz H. ^{[1
]}

机构：

[1] Heidelberg Univ, Anorgan Chem Inst, D-69120 Heidelberg, Germany

来源：

ORGANOMETALLICS | 2025年 / 44卷 / 13期

关键词：

PARAMAGNETIC-SUSCEPTIBILITY; TRANSITION-METAL; H BOND; DIHYDROBORATION; MECHANISM; ALKYNES; SCOPE; HYDROSILYLATION; PRECATALYSTS; ACTIVATION;

D O I：

10.1021/acs.organomet.5c00134

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iron(II) alkyl complexes of a terdentate bisoxazoline pincer ligand ("boxmi") were synthesized, structurally characterized, and applied as precatalysts in the hydroboration of nitriles. By limiting the amount of borane, dinitriles could be partially hydroborated to selectively give the aminonitriles. Iron(I) complexes stabilized by dimerization were identified as an off-cycle species of the catalysis and characterized. Reactivity studies showed the iron(I) dimer reacting with ligands possessing at least some pi-acceptor character, such as pyridine, Ph-C C-Ph and CO, to form monomeric adduct complexes that were isolated and structurally characterized.

引用

页码：1458 / 1466

页数：9

共 87 条

[71] Catalytic Recycling of a Th-H Bond via Single or Double Hydroboration of Inactivated (mines or Nitriles [J].

Saha, Sayantani ;

Eisen, Moris S. .

ACS CATALYSIS, 2019, 9 (07) :5947-5956

[72] Zinc Hydride-Catalyzed Dihydroboration of Isonitriles and Nitriles: Mechanistic Studies with the Structurally Characterized Zinc Intermediates [J].

Sahoo, Rajata Kumar ;

Rajput, Sagrika ;

Dutta, Sneha ;

Sahu, Kasturi ;

Nembenna, Sharanappa .

ORGANOMETALLICS, 2023, 42 (16) :2293-2303

[73] Aluminum-Catalyzed Selective Hydroboration of Nitriles and Alkynes: A Multifunctional Catalyst [J].

Sarkar, Nabin ;

Bera, Subhadeep ;

Nembenna, Sharanappa .

JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (07) :4999-5009

[74] Effective Magnesium-catalyzed Hydroboration of Nitriles and Imines [J].

Seok, Ji Eun ;

Kim, Hyun Tae ;

Kim, Jaeho ;

Lee, Ji Hye ;

Jaladi, Ashok Kumar ;

Hwang, Hyonseok ;

An, Duk Keun .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (10)

[75] Frustrated Lewis Pair-Catalyzed Hydroboration of Nitriles: FLP Versus Borenium Catalysis [J].

Sieland, Benedikt ;

Hoppe, Axel ;

Stepen, Arne J. ;

Paradies, Jan .

ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (18) :3143-3148

[76] Low-valent-tungsten catalysis enables hydroboration of esters and nitriles [J].

Song, Heng ;

Xiao, Yuting ;

Wei, Jingjing ;

Liu, Yuzan ;

Yang, Liqing ;

Bai, Pengtao ;

Yang, Fu ;

Yu, Kai ;

Xu, Chen ;

Cai, Xingwei .

CHEMICAL COMMUNICATIONS, 2024, 60 (38) :5026-5029

[77] MEASUREMENT OF MAGNETIC-SUSCEPTIBILITY AND MAGNETIC-MOMENT OF PARAMAGNETIC MOLECULES IN SOLUTION BY HIGH-FIELD FOURIER-TRANSFORM NMR-SPECTROSCOPY [J].

SUR, SK .

JOURNAL OF MAGNETIC RESONANCE, 1989, 82 (01) :169-173

[78] Hydroboration of Nitriles, Esters, and Carbonates Catalyzed by Simple Earth-Abundant Metal Triflate Salts [J].

Thenarukandiyil, Ranjeesh ;

Satheesh, Vanaparthi ;

Shimon, Linda J. W. ;

de Ruiter, Graham .

CHEMISTRY-AN ASIAN JOURNAL, 2021, 16 (08) :999-1006

[79] A robust Zintl cluster for the catalytic reduction of pyridines, imines and nitriles [J].

van IJzendoorn, Bono ;

Whittingham, Jessica B. M. ;

Whitehead, George F. S. ;

Kaltsoyannis, Nikolas ;

Mehta, Meera .

DALTON TRANSACTIONS, 2023, 52 (38) :13787-13796

[80] Borohydride intermediates pave the way for magnesium-catalysed enantioselective ketone reduction [J].

Vasilenko, Valdislav ;

Blasius, Clemens K. ;

Wadepohl, Hubert ;

Gade, Lutz H. .

CHEMICAL COMMUNICATIONS, 2020, 56 (08) :1203-1206

← 1 2 3 4 5 6 7 8 9 →