A comparative analysis of the removal of arsenic from water using magnetite/polyaniline-polypyrrole nanocomposite

被引:0
作者
Jabeen, T. [1 ]
Rashid, M. [2 ]
Khan, A. [3 ]
Haider, S. [2 ]
Aslam, M. [3 ]
Shahid, E. [4 ]
Shahid, H. [5 ]
Al-Ansari, N. [6 ]
Mattar, M. A. [7 ,8 ]
机构
[1] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[2] Univ Engn & Technol, Ctr Excellence Water Resources Engn, Lahore 54890, Pakistan
[3] Univ Lahore, Govt Coll, Lahore 54000, Punjab, Pakistan
[4] Univ Agr Faisalabad, Dept Chem, Sub Campus Burewala, Burewala, Pakistan
[5] Tech Univ Dresden, Dept Biochem, Dresden, Germany
[6] Lulea Univ Technol, Dept Civil Environm & Nat Resources Engn, S-97187 Lulea, Sweden
[7] King Saud Univ, Prince Sultan Inst Environm Water & Desert Res, Prince Sultan Bin Abdulaziz Int Prize Water Chair, Riyadh 11451, Saudi Arabia
[8] King Saud Univ, Coll Food & Agr Sci, Agr Engn Dept, POB 2460, Riyadh 11451, Saudi Arabia
关键词
Arsenic; Nanocomposite; Water pollution; Adsorption; Magnetite nanoparticles; Polymers; MAGNETIC NANOPARTICLES; EFFICIENT REMOVAL; OXIDE; ADSORBENT; COMPOSITE; PERFORMANCE; ADSORPTION; BINDING; FE3O4;
D O I
10.1007/s13762-025-06573-4
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Arsenic contamination in groundwater, particularly in developing countries like Pakistan, poses significant health risks, including developmental abnormalities, cardiovascular ailments, and cancer. It also affects aquatic biodiversity, agricultural production, and soil quality, endangering ecosystems and posing a global concern. Various methods like ion exchange, membrane filtration, precipitation, photocatalytic degradation, and adsorption have been explored for arsenic removal, with adsorption proving to be the most effective. This research not only introduces a novel material for water purification but also provides a sustainable and cost-effective alternative to traditional treatment methods. A magnetite/polyaniline-polypyrrole nanocomposite with improved adsorption effectiveness has been created to address the challenge of arsenic removal. By combining inorganic iron oxide with organic conducting polymers, oxidative polymerization of polypyrrole and aniline was achieved in the presence of magnetite (Fe3O4). Magnetite is used to facilitate separation from treated water, which lowers the production of secondary waste and increases treatment efficiency overall. The nanocomposite was characterized using FTIR, SEM, XRD, TGA, DSC, Raman spectroscopy, UV-visible, and BET techniques. The colorimetric method confirmed arsenic removal, with further spectrophotometric analysis showing a 92% reduction of arsenic from an aqueous solution using just 0.01 g of the adsorbent at pH 1. The magnetite/polyaniline-polypyrrole nanocomposite offers an effective solution for arsenic removal, warranting further research and optimization for practical applications in arsenic-contaminated regions. This study supports Clean Water and Sanitation that seek to guarantee to access clean and sanitary water for drinking. The results of this study can be used to large-scale water treatment projects, which will help communities whose water supplies are tainted by arsenic.
引用
收藏
页数:20
相关论文
共 57 条
[1]   Polypyrrole-polyaniline/Fe3O4 magnetic nanocomposite for the removal of Pb(II) from aqueous solution [J].
Afshar, Amirhossein ;
Sadjadi, Seyed Abolfazl Seyed ;
Mollahosseini, Afsaneh ;
Eskandarian, Mohammad Reza .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (02) :669-677
[2]  
Amin Kazi Faiza, 2023, Environmental Nanotechnology, Monitoring and Management, V20, DOI 10.1016/j.enmm.2023.100801
[3]  
Amin KF., 2022, Synthesis of novel magnetite nanoparticles with chitosan mesoporous silica coating for efficient removal of heavy metals from wastewater
[4]   Synthesis and characterization of a new class of polymeric ligand exchangers for selective removal of arsenate from drinking water [J].
An, Byungryul ;
Fu, Zengli ;
Xiong, Zhong ;
Zhao, Dongye ;
SenGupta, Arup K. .
REACTIVE & FUNCTIONAL POLYMERS, 2010, 70 (08) :497-507
[5]   Synthesised magnetic nanoparticles coated zeolite (MNCZ) for the removal of arsenic (As) from aqueous solution [J].
Attia, Tamer Mohamed Salem ;
Hu, Xia Lin ;
Yin, Da Qiang .
JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2014, 9 (06) :551-560
[6]   Synthesis, characterization of Fe3O4@glycine doped polypyrrole magnetic nanocomposites and their potential performance to remove toxic Cr(VI) [J].
Ballav, N. ;
Choi, H. J. ;
Mishra, S. B. ;
Maity, A. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2014, 20 (06) :4085-4093
[7]   Magnetically recyclable L-cysteine capped Fe3O4 nanoadsorbent: A promising pH guided removal of Pb(II), Zn(II) and HCrO4- contaminants [J].
Bashir, Arshid ;
Pandith, Altaf Hussain ;
Malik, Lateef Ahmad ;
Qureashi, Aaliya ;
Ganaie, Firdous Ahmad ;
Dar, Ghulam Nabi .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (05)
[8]   A review on nanotechnological application of magnetic iron oxides for heavy metal removal [J].
Bhateria, Rachna ;
Singh, Rimmy .
JOURNAL OF WATER PROCESS ENGINEERING, 2019, 31
[9]   Polyaniline/Fe0 composite nanofibers: An excellent adsorbent for the removal of arsenic from aqueous solutions [J].
Bhaumik, Madhumita ;
Noubactep, Chicgoua ;
Gupta, Vinod Kumar ;
McCrindle, Rob I. ;
Maity, Arjun .
CHEMICAL ENGINEERING JOURNAL, 2015, 271 :135-146
[10]   Enhanced removal of Cr(VI) from aqueous solution using polypyrrole/Fe3O4 magnetic nanocomposite [J].
Bhaumik, Madhumita ;
Maity, Arjun ;
Srinivasu, V. V. ;
Onyango, Maurice S. .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 190 (1-3) :381-390