Experimental Liquid Densities of Red Palm Oil at Pressures up to 150 MPa from (312 to 352) K and Dynamic Viscosities at 0.1 MPa from (293 to 353) K

被引:0
作者
Lee, Jia Lin [1 ,2 ]
Chong, Gun Hean [1 ,2 ]
Hiraga, Yuya [3 ]
Sato, Yoshiyuki [4 ]
Ota, Masaki [3 ,5 ]
Smith Jr, Richard Lee [5 ]
机构
[1] Univ Putra Malaysia, Fac Food Sci & Technol, Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Fac Food Sci & Technol, Supercrit Fluid Ctr SFC, Serdang 43400, Selangor, Malaysia
[3] Tohoku Univ, Grad Sch Engn, Aramaki Aza Aoba 6-6-11-403,Aoba Ku, Sendai 9808579, Japan
[4] Tohoku Inst Technol, Fac Engn, Dept Appl Chem & Environm, 35-1 Yagiyama Kasumi Cho,Taihaku Ku, Sendai 9828577, Japan
[5] Tohoku Univ, Grad Sch Environm Studies, Aramaki Aza Aoba 468-1,Aoba Ku, Sendai 9808572, Japan
来源
LIQUIDS | 2025年 / 5卷 / 02期
关键词
red palm oil; density; viscosity; pressure; temperature; FLUID PROPERTIES; VEGETABLE-OILS; TEMPERATURE; DEPENDENCE; EQUATION; PREDICTION;
D O I
10.3390/liquids5020013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Density and viscosity are fundamental properties necessary for processing of red palm oil (RPO). The main fatty acid constituents of RPO were determined to be palmitic acid (C16:0), oleic acid (C18:1), and linoleic acid (C18:2). Rheology measurements confirmed that RPO behaved as a Newtonian fluid. Viscosities and atmospheric densities of RPO were measured at 0.1 MPa and (293 K to 413) K and correlated with the Rodenbush model (0.05% deviation). Dynamic viscosities of RPO were correlated with the Vogel-Fulcher-Tammann model (0.06% deviation) and Doolittle free volume model (0.04% deviation). High-pressure densities of RPO were measured at (10 to 150) MPa and (312 to 352) K. The Tait equation could correlate the high-pressure densities of RPO to within 0.021% deviation and was used to estimate the thermal expansion as 5.1 x 10-4 K-1 (at 312 K, 150 MPa) to 4.8 x 10-4 K-1 (at 352 K, 150 MPa) and isothermal compressibility as 7.3 x 10-4 MPa-1 (at 352 K, 0.1 MPa) to 3.5 x 10-4 MPa-1 (at 352 K, 150 MPa). Parameters for the perturbed-chain statistical associating fluid theory equation of state were determined and gave an average of 0.143% deviation in density. The data and equations developed should be useful in high-pressure food processing as well as in applications considering vegetable oils as heat transfer fluids or as lubricants.
引用
收藏
页数:14
相关论文
共 32 条
[1]   Fluid properties needed in supercritical transesterification of triglyceride feedstocks to biodiesel fuels for efficient and clean combustion - A review [J].
Anitescu, George ;
Bruno, Thomas J. .
JOURNAL OF SUPERCRITICAL FLUIDS, 2012, 63 :133-149
[2]   Liquid Biofuels: Fluid Properties to Optimize Feedstock Selection, Processing, Refining/Blending, Storage/Transportation, and Combustion [J].
Anitescu, George ;
Bruno, Thomas J. .
ENERGY & FUELS, 2012, 26 (01) :324-348
[3]  
Brhl L., 1997, Lipid/Fett, V99, P197, DOI [10.1002/lipi.19970990510, DOI 10.1002/LIPI.19970990510]
[4]   Influence of triacylglycerol structure on the formation of lipid oxidation products in different vegetable oils during frying process [J].
Chen, Jia ;
Zhang, Lingyan ;
Guo, Xingfeng ;
Qiang, Jie ;
Cao, Yongsheng ;
Zhang, Siyu ;
Yu, Xiuzhu .
FOOD CHEMISTRY, 2025, 464
[5]   Thermal and Physical Properties of Crude Palm Oil with Higher Oleic Content [J].
de Almeida, Erislene S. ;
Damaceno, Daniela da Silva ;
Carvalho, Laiane ;
Victor, Priscilla Araujo ;
dos Passos, Rafaela Menezes ;
de Almeida Pontes, Paula Virginia ;
Cunha-Filho, Marcilio ;
Sampaio, Klicia A. ;
Monteiro, Simone .
APPLIED SCIENCES-BASEL, 2021, 11 (15)
[6]   STUDIES IN NEWTONIAN FLOW .2. THE DEPENDENCE OF THE VISCOSITY OF LIQUIDS ON FREE-SPACE [J].
DOOLITTLE, AK .
JOURNAL OF APPLIED PHYSICS, 1951, 22 (12) :1471-1475
[7]   Temperature dependence of density and viscosity of vegetable oils [J].
Esteban, Bernat ;
Riba, Jordi-Roger ;
Baquero, Grau ;
Rius, Antoni ;
Puig, Rita .
BIOMASS & BIOENERGY, 2012, 42 :164-171
[8]  
Ferrari G., 2017, Chem. Eng. Trans, V57, P1831, DOI [10.3303/CET1757306, DOI 10.3303/CET1757306]
[9]   Experimental investigation of the effect of fatty acids configuration, chain length, branching and degree of unsaturation on biodiesel fuel properties obtained from lauric oils, high-oleic and high-linoleic vegetable oil biomass [J].
Folayan, Adewale Johnson ;
Anawe, Paul Apeye Lucky ;
Aladejare, Adeyemi Emman ;
Ayeni, Augustine Omoniyi .
ENERGY REPORTS, 2019, 5 :793-806
[10]   Measurement and Prediction of Densities of Vegetable Oils at Pressures up to 45 MPa [J].
Freitas, Samuel V. D. ;
Silva, Francisca A. e ;
Jose Pastoriza-Gallego, Maria ;
Pineiro, Manuel M. ;
Lima, Alvaro S. ;
Coutinho, Joao A. P. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2013, 58 (11) :3046-3053