Microporous activated carbon from Madhuca Longifolia flower for efficient methylene blue dye removal in wastewater treatment

被引:2
作者
Mishra, Shiv Rag [1 ,2 ]
Mandal, Tuhin [1 ,2 ]
Kumar, Praveen [3 ]
Verma, Vivek [3 ]
Senapati, Rabi Narayan [1 ]
Kumar, Manish [1 ,2 ]
Singh, Vikram [1 ,2 ,4 ]
机构
[1] Cent Inst Min & Fuel Res, CSIR, Environm Emiss & CRM Sect, Dhanbad 828108, Jharkhand, India
[2] Acad Sci & Innovat Res, Ghaziabad 201002, India
[3] Indian Inst Technol Kanpur, Dept Mat Sci & Engn, Kanpur 208016, UP, India
[4] Indian Inst Toxicol Res, CSIR, ASSIST Div, Analyt Sci Res Grp, 31 MG Marg, Lucknow 226001, Uttar Pradesh, India
关键词
Microporous activated carbon; Madhuca longifolia flower; Chemical activation; Adsorption isotherm; Wastewater dye removal; Methylene blue removal; ADSORPTION; POLLUTANTS; BIOMASS;
D O I
10.1016/j.surfin.2025.106770
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work focuses on developing microporous-activated carbon from the cost-effective Madhuca Longifolia flower using the potassium hydroxide activator at an activation temperature of 750 degrees C to remove methylene blue dye from an aqueous medium. The pore size, morphology, elemental composition, and specific surface area were analyzed using field emission scanning electron microscopy and the Brunauer-Emmett-Teller method. The prepared activated carbon showed a well-developed microstructure with a specific surface area of 764.68 m2/g. Fourier transform infrared spectroscopic study confirmed the alcoholic and carboxylic hydroxyl groups, which play a vital role in the adsorption kinetics. The pseudo-second-order kinetic model investigation revealed that chemical adsorption was the most important factor in this adsorption study. The Langmuir isotherm model fits this study's equilibrium data well and concludes that the Methylene Blue adsorption process might be a homogeneous monolayer adsorption. The developed activated carbon exhibited high absorptivity, with a maximum adsorption capacity of 168.54 mg/g for methylene blue dye in the aqueous medium. These findings confirmed that the sustainable and low-cost Madhuca Longifolia flower-derived activated carbon has a promising potential for removing pollutants such as methylene blue dye in drinking water.
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页数:10
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共 53 条
[1]   Cost effective biosynthetic approach for graphene exhibiting superior sonochemical dye removal capacity [J].
Akhil, Syed ;
Saeed, Al Musawi Mahdi Jawad ;
Majety, Syam Sundar ;
Mullamuri, Bhanu ;
Majji, Ganesh ;
Bharatiya, Debasrita ;
Mosali, Venkata Sai Sriram ;
Bollikolla, Hari Babu ;
Chandu, Basavaiah .
CARBON LETTERS, 2021, 31 (06) :1215-1225
[2]   Water defluoridation with avocado-based adsorbents: Synthesis, physicochemical characterization and thermodynamic studies [J].
Angel Salomon-Negrete, Miguel ;
Elizabeth Reynel-Avila, Hilda ;
Ileana Mendoza-Castillo, Didilia ;
Bonilla-Petriciolet, Adrian ;
Javier Duran-Valle, Carlos .
JOURNAL OF MOLECULAR LIQUIDS, 2018, 254 :188-197
[3]   Experimental methods in chemical engineering: specific surface area and pore size distribution measurements-BET, BJH, and DFT [J].
Bardestani, Raoof ;
Patience, Gregory S. ;
Kaliaguine, Serge .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2019, 97 (11) :2781-2791
[4]   Treatment of pollutants in wastewater: Adsorption of methylene blue onto olive-based activated carbon [J].
Berrios, Monica ;
Angeles Martin, Maria ;
Martin, Antonio .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (02) :780-784
[5]   Recent advances in biomass derived activated carbon electrodes for hybrid electrochemical capacitor applications: Challenges and opportunities [J].
Dubey, Prashant ;
Shrivastav, Vishal ;
Maheshwari, Priyanka H. ;
Sundriyal, Shashank .
CARBON, 2020, 170 :1-29
[6]   TiO2 and activated carbon of Argania Spinosa tree nutshells composites for the adsorption photocatalysis removal of pharmaceuticals from aqueous solution [J].
El Mouchtari, El Mountassir ;
Daou, Claude ;
Rafqah, Salah ;
Najjar, Fadia ;
Anane, Hafid ;
Piram, Anne ;
Hamade, Aline ;
Briche, Samir ;
Wong-Wah-Chung, Pascal .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2020, 388
[7]   Advanced microcrystalline nanocellulose-based nanofiltration membranes for the efficient treatment of wastewater contaminated with cationic dyes [J].
El-Sawaf, Ayman K. ;
Nassar, Amal A. ;
Elfiky, Aya Abd El Aziz ;
Mubarak, Mahmoud F. .
POLYMER BULLETIN, 2024, 81 (14) :12451-12476
[8]   Novel nanofiltration membrane modified by metal oxide nanocomposite for dyes removal from wastewater [J].
Elfiky, Aya Abd El Aziz ;
Mubarak, Mahmoud F. ;
Keshawy, Mohamed ;
Sayed, Ibrahim El Tantawy El ;
Moghny, Thanaa Abdel .
ENVIRONMENT DEVELOPMENT AND SUSTAINABILITY, 2024, 26 (08) :19935-19957
[9]   Electrochemical removal of methylene blue using alginate-modified graphene adsorbents [J].
Fadillah, Ganjar ;
Saleh, Tawfik A. ;
Wahyuningsih, Sayekti ;
Putri, Elsa Ninda Karlina ;
Febrianastuti, Syahna .
CHEMICAL ENGINEERING JOURNAL, 2019, 378
[10]   Biomass-Based Activated Carbon and Activators: Preparation of Activated Carbon from Corncob by Chemical Activation with Biomass Pyrolysis Liquids [J].
Feng, Ping ;
Li, Jie ;
Wang, Huan ;
Xu, Zhiqiang .
ACS OMEGA, 2020, 5 (37) :24064-24072