Cation reactivity inhibits perovskite degradation in efficient and stable solar modules

被引：29

作者：

Ding, Yong ^{[1
,2
]}

Ding, Bin ^{[2
,3
]}

Shi, Pengju ^{[4
]}

Romano-deGea, Jan ^{[2
]}

Li, Yahui ^{[4
]}

Turnell-Ritson, Roland C. ^{[2
]}

Syzgantseva, Olga A. ^{[5
]}

Yavuz, Ilhan ^{[6
]}

Xia, Ming ^{[4
]}

Yu, Ruohan ^{[7
]}

Syzgantseva, Maria A. ^{[8
]}

Audinot, Jean-Nicolas ^{[9
]}

Miao, Xiaohe ^{[4
]}

Liao, Xiaobin ^{[7
]}

Li, Jiantao ^{[10
]}

Doerflinger, Patrick ^{[11
]}

Dyakonov, Vladimir ^{[11
]}

Liu, Cheng ^{[1
]}

Yang, Yi ^{[1
]}

Tao, Li ^{[12
]}

Brooks, Keith G. ^{[2
]}

Slonopas, Andre ^{[13
]}

Pan, Jiahong ^{[14
]}

Zhang, Lei ^{[7
]}

An, Qinyou ^{[7
]}

Rong, Yaoguang ^{[7
]}

Peng, Jun ^{[3
]}

Ding, Liming ^{[15
]}

Shi, Enzheng ^{[4
]}

Mai, Liqiang ^{[7
]}

Dai, Songyuan ^{[1
]}

Zhao, Kangning ^{[2
,7
]}

Sheng, Jiang ^{[16
]}

Wang, Rui ^{[4
]}

Dyson, Paul J. ^{[2
]}

Nazeeruddin, Mohammad Khaja ^{[2
]}

机构：

[1] North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China

[2] Ecole Polytech Fed Lausanne EPFL, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[3] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[4] Westlake Univ, Sch Engn, Hangzhou 310024, Peoples R China

[5] Lomonosov Moscow State Univ, Dept Chem, Moscow 119991, Russia

[6] Marmara Univ, Dept Phys, TR-34722 Istanbul, Turkiye

[7] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China

[8] Mendeleev Univ Chem Technol, Moscow 125047, Russia

[9] Luxembourg Inst Sci & Technol LIST, Dept Mat Res & Technol, Adv Instrumentat Nanoanalyt AINA, L-4422 Belvaux, Luxembourg

[10] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

[11] Univ Wurzburg, Expt Phys 6, D-97074 Wurzburg, Germany

[12] Hubei Univ, Sch Microelect, Wuhan 430062, Peoples R China

[13] Johns Hopkins Univ, Whiting Sch Engn, Dept Mat Sci & Engn, Baltimore, MD 21218 USA

[14] Guangxi Univ, State Key Lab Featured Met Mat & Life cycle Safety, Nanning 530004, Peoples R China

[15] Chinese Acad Sci, Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China

[16] Changzhou Inst Technol, Changzhou 213002, Peoples R China

来源：

SCIENCE | 2024年 / 386卷 / 6721期

基金：

中国国家自然科学基金; 瑞士国家科学基金会;

关键词：

CELLS; FILMS;

D O I：

10.1126/science.ado6619

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Perovskite solar modules (PSMs) show outstanding power conversion efficiencies (PCEs), but long-term operational stability remains problematic. We show that incorporating N,N-dimethylmethyleneiminium chloride into the perovskite precursor solution formed dimethylammonium cation and that previously unobserved methyl tetrahydrotriazinium ([MTTZ](+)) cation effectively improved perovskite film. The in situ formation of [MTTZ](+) cation increased the formation energy of iodine vacancies and enhanced the migration energy barrier of iodide and cesium ions, which suppressed nonradiative recombination, thermal decomposition, and phase segregation processes. The optimized PSMs achieved a record (certified) PCE of 23.2% with an aperture area of 27.2 cm(2), with a stabilized PCE of 23.0%. The encapsulated PSM retained 87.0% of its initial PCE after similar to 1900 hours of maximum power point tracking at 85 degrees C and 85% relative humidity under 1.0-sun illumination.

引用

页码：531 / 538

页数：8

共 41 条

[1] A Highly Emissive Surface Layer in Mixed-Halide Multication Perovskites [J].

Andaji-Garmaroudi, Zahra ;

Abdi-Jalebi, Mojtaba ;

Guo, Dengyang ;

Macpherson, Stuart ;

Sadhanala, Aditya ;

Tennyson, Elizabeth M. ;

Ruggeri, Edoardo ;

Anaya, Miguel ;

Galkowski, Krzysztof ;

Shivanna, Ravichandran ;

Lohmann, Kilian ;

Frohna, Kyle ;

Mackowski, Sebastian ;

Savenije, Tom J. ;

Friend, Richard H. ;

Stranks, Samuel D. .

ADVANCED MATERIALS, 2019, 31 (42)

[2] Damp heat-stable perovskite solar cells with tailored-dimensionality 2D/3D heterojunctions [J].

Azmi, Randi ;

Ugur, Esma ;

Seitkhan, Akmaral ;

Aljamaan, Faisal ;

Subbiah, Anand S. ;

Liu, Jiang ;

Harrison, George T. ;

Nugraha, Mohamad, I ;

Eswaran, Mathan K. ;

Babics, Maxime ;

Chen, Yuan ;

Xu, Fuzong ;

Allen, Thomas G. ;

Rehman, Atteq Ur ;

Wang, Chien-Lung ;

Anthopoulos, Thomas D. ;

Schwingenschlogl, Udo ;

De Bastiani, Michele ;

Aydin, Erkan ;

De Wolf, Stefaan .

SCIENCE, 2022, 376 (6588) :73-+

[3] Initializing film homogeneity to retard phase segregation for stable perovskite solar cells [J].

Bai, Yang ;

Huang, Zijian ;

Zhang, Xiao ;

Lu, Jiuzhou ;

Niu, Xiuxiu ;

He, Ziwen ;

Zhu, Cheng ;

Xiao, Mengqi ;

Song, Qizhen ;

Wei, Xueyuan ;

Wang, Chenyue ;

Cui, Zhenhua ;

Dou, Jing ;

Chen, Yihua ;

Pei, Fengtao ;

Zai, Huachao ;

Wang, Wei ;

Song, Tinglu ;

An, Pengfei ;

Zhang, Jing ;

Dong, Juncai ;

Li, Yiming ;

Shi, Jiangjian ;

Jin, Haibo ;

Chen, Pengwan ;

Sun, Yuchao ;

Li, Yujing ;

Chen, Haining ;

Wei, Zhongming ;

Zhou, Huanping ;

Chen, Qi .

SCIENCE, 2022, 378 (6621) :747-754

[4] Modulating crystal growth of formamidinium-caesium perovskites for over 200 cm2 photovoltaic sub-modules [J].

Bu, Tongle ;

Ono, Luis K. ;

Li, Jing ;

Su, Jie ;

Tong, Guoqing ;

Zhang, Wei ;

Liu, Yuqiang ;

Zhang, Jiahao ;

Chang, Jingjing ;

Kazaoui, Said ;

Huang, Fuzhi ;

Cheng, Yi-Bing ;

Qi, Yabing .

NATURE ENERGY, 2022, 7 (06) :528-536

[5] Dopant-additive synergism enhances perovskite solar modules [J].

Ding, Bin ;

Ding, Yong ;

Peng, Jun ;

Romano-deGea, Jan ;

Frederiksen, Lindsey E. K. ;

Kanda, Hiroyuki ;

Syzgantseva, Olga A. ;

Syzgantseva, Maria A. ;

Audinot, Jean-Nicolas ;

Bour, Jerome ;

Zhang, Song ;

Wirtz, Tom ;

Fei, Zhaofu ;

Doerflinger, Patrick ;

Shibayama, Naoyuki ;

Niu, Yunjuan ;

Hu, Sixia ;

Zhang, Shunlin ;

Tirani, Farzaneh Fadaei ;

Liu, Yan ;

Yang, Guan-Jun ;

Brooks, Keith ;

Hu, Linhua ;

Kinge, Sachin ;

Dyakonov, Vladimir ;

Zhang, Xiaohong ;

Dai, Songyuan ;

Dyson, Paul J. ;

Nazeeruddin, Mohammad Khaja .

NATURE, 2024, 628 (8007) :299-305

[6] Understanding the Degradation of Methylenediammonium and Its Role in Phase-Stabilizing Formamidinium Lead Triiodide [J].

Duijnstee, Elisabeth A. ;

Gallant, Benjamin M. ;

Holzhey, Philippe ;

Kubicki, Dominik J. ;

Collavini, Silvia ;

Sturdza, Bernd K. ;

Sansom, Harry C. ;

Smith, Joel ;

Gutmann, Matthias J. ;

Saha, Santanu ;

Gedda, Murali ;

Nugraha, Mohamad I. ;

Kober-Czerny, Manuel ;

Xia, Chelsea ;

Wright, Adam D. ;

Lin, Yen-Hung ;

Ramadan, Alexandra J. ;

Matzen, Andrew ;

Hung, Esther Y. -H. ;

Seo, Seongrok ;

Zhou, Suer ;

Lim, Jongchul ;

Anthopoulos, Thomas D. ;

Filip, Marina R. ;

Johnston, Michael B. ;

Nicholas, Robin J. ;

Delgado, Juan Luis ;

Snaith, Henry J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (18) :10275-10284

[7] Ionic transport in hybrid lead iodide perovskite solar cells [J].

Eames, Christopher ;

Frost, Jarvist M. ;

Barnes, Piers R. F. ;

O'Regan, Brian C. ;

Walsh, Aron ;

Islam, M. Saiful .

NATURE COMMUNICATIONS, 2015, 6

[8] Polarity-Differentiated Dielectric Materials in Monolayer Graphene Charge-Regulated Field-Effect Transistors for an Artificial Reflex Arc and Pain-Modulation System of the Spinal Cord [J].

Fu, Yi ;

Chan, Ya-Ting ;

Jiang, Yi-Pei ;

Chang, Kuo-Hsuan ;

Wu, Hsiu-Chuan ;

Lai, Chao-Sung ;

Wang, Jer-Chyi .

ADVANCED MATERIALS, 2022, 34 (30)

[9] How far are we from attaining 10-year lifetime for metal halide perovskite solar cells? [J].

He, Sisi ;

Qiu, Longbin ;

Ono, Luis K. ;

Qi, Yabing .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2020, 140

[10] Large guanidinium cation mixed with methylammonium in lead iodide perovskites for 19% efficient solar cells [J].

Jodlowski, Alexander D. ;

Roldan-Carmona, Cristina ;

Grancini, Giulia ;

Salado, Manuel ;

Ralaiarisoa, Maryline ;

Ahmad, Shahzada ;

Koch, Norbert ;

Camacho, Luis ;

de Miguel, Gustavo ;

Nazeeruddin, Mohammad Khaja .

NATURE ENERGY, 2017, 2 (12) :972-979

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