Recent Advances in Carbon-Based Catalysts for Heterogeneous Asymmetric Catalysis

被引：0

作者：

Zheng, Yidan ^{[1
]}

Liu, Tianze ^{[1
]}

Tai, Jingyou ^{[1
]}

Ma, Ning ^{[1
]}

机构：

[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin 300072, Peoples R China

来源：

MOLECULES | 2025年 / 30卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbon material; graphene; carbon nanotube; asymmetric catalysis; ACTIVATED CARBON; CHIRAL CATALYST; SALEN COMPLEXES; PI-STACKING; NANOTUBES; HYDROGENATION; DOTS; IMMOBILIZATION; NANOPARTICLES; OXIDE;

D O I：

10.3390/molecules30122643

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Carbon materials, including graphene, carbon nanotubes, and fullerenes, serve as effective supports for catalysts and play a pivotal role in heterogeneous asymmetric catalysis due to their unique properties and ability to create defined environments for catalytic reactions. Recent research has focused on developing novel carbon-based catalysts that combine the advantages of heterogeneous catalysis with enhanced stability and reusability. This review highlights the synthesis and catalytic applications of graphene, carbon nanotubes, and fullerenes as heterogeneous support materials in asymmetric organocatalytic and organometallic reactions, covering their mechanisms, efficiency, and potential for advancing sustainable chemical processes.

引用

页数：20

共 68 条

[1] A heterogenized chiral imino indanol complex of manganese as an efficient catalyst for aerobic epoxidation of olefins [J].

Abbasi, Vahideh ;

Hosseini-Monfared, Hassan ;

Hosseini, Seyed Majid .

NEW JOURNAL OF CHEMISTRY, 2017, 41 (18) :9866-9874

[2] Recyclable Chiral Bifunctional Thioureas Derived from [60]Fullerene and Their Use as Highly Efficient Organocatalysts for the Asymmetric Nitro-Michael Reaction [J].

Andres, Jose M. ;

Gonzalez, Miguel ;

Maestro, Alicia ;

Naharro, Daniel ;

Pedrosa, Rafael .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (19) :2683-2691

[3] Valmet Chiral Schiff-Base Ligands And Their Copper(II) Complexes as Organo, Homogeneous and Heterogeneous Catalysts for Henry, Cyanosilylation and Aldol Coupling Reactions [J].

Arora, Zinnia ;

Eftemie, Diana-Ioana ;

Spinciu, Adela ;

Maxim, Catalin ;

Hanganu, Ana-Maria ;

Tudorache, Madalina ;

Cojocaru, Bogdan ;

Pavel, Octavian D. ;

Granger, Pascal ;

Andruh, Marius ;

Parvulescu, Vasile, I .

CHEMCATCHEM, 2021, 13 (21) :4634-4644

[4] Graphene-based recyclable and bifunctional heterogeneous chiral catalyst for direct asymmetric aldol reaction [J].

Azlouk, Manel ;

Durmaz, Mustafa ;

Zor, Erhan ;

Bingol, Haluk .

MATERIALS CHEMISTRY AND PHYSICS, 2020, 239

[5] Fundamental Investigations of Enantioselective Heterogeneous Catalysis [J].

Baddeley, Christopher J. ;

Jones, Timothy E. ;

Trant, Aoife G. ;

Wilson, Karen E. .

TOPICS IN CATALYSIS, 2011, 54 (19-20) :1348-1356

[6] Primary amine-thiourea grafted graphene-based heterogeneous chiral catalysts for highly enantioselective Michael additions [J].

Badr, Sayed Mustafa ;

Azlouk, Manel ;

Zor, Erhan ;

Bingol, Haluk ;

Durmaz, Mustafa .

MOLECULAR CATALYSIS, 2022, 526

[7] Luminescent Carbon Nanodots: Emergent Nanolights [J].

Baker, Sheila N. ;

Baker, Gary A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6726-6744

[8] Vanadyl salen complexes covalently anchored to single-wall carbon nanotubes as heterogeneous catalysts for the cyanosilylation of aldehydes [J].

Baleizao, C ;

Gigante, B ;

Garcia, H ;

Corma, A .

JOURNAL OF CATALYSIS, 2004, 221 (01) :77-84

[9] Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts [J].

Baleizao, Carlos ;

Garcia, Hermenegildo .

CHEMICAL REVIEWS, 2006, 106 (09) :3987-4043

[10] Chiral Carbon Nanodots Can Act as Molecular Catalysts in Chemical and Photochemical Reactions [J].

Bartolomei, Beatrice ;

Corti, Vasco ;

Prato, Maurizio .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (32)

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