Investigation of Simple and Complex Reaction Kinetics with a Simulated Program by LabVIEW

被引:0
作者
Liu, Li [1 ]
Fu, Qiang [1 ]
Gao, Qingsheng [2 ,3 ]
机构
[1] Jiangxi Coll Tradit Chinese Med, Dept Math Phys & Chem, Fuzhou 344000, Jiangxi, Peoples R China
[2] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 510632, Peoples R China
[3] Jinan Univ, Guangdong Prov Key Lab Funct Supramol Coordinat Ma, Guangzhou 510632, Peoples R China
关键词
Physical Chemistry; Computer-Based Learning; Distance Learning/Self Instruction; Chemical Kinetics; Upper-Division Undergraduate; Rate Law; Reactions; Mathematics/Symbolic Mathematics; ENZYME-KINETICS; CHEMICAL-KINETICS; COMPUTER-SIMULATION; INTEGRATION; ABSORBENCY; TITRATION; INQUIRY; SYSTEM;
D O I
10.1021/acs.jchemed.4c01332
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chemical reaction kinetics simulation program was developed to simulate both simple and complex reactions with LabVIEW. In the case of simple reactions, the focus is on the kinetic characteristics of dual-reactant systems with different stoichiometric ratios at initial concentrations. For complex reactions, the characteristics of parallel, consecutive, reversible, and autocatalytic reactions are discussed. The numerical simulations from the program are close to the analytical solutions and can effectively reflect the kinetic characteristics of different types of reactions. The effectiveness of the simulation program in promoting learning was verified by experimental and control groups, and the score rate of the experimental group (89.7%) was significantly higher than that of the control group (66.6%). The results indicate that, with the help of the program, students can better construct the differential equations based on the law of mass action and understand the kinetic plots of different reactions as well as the relationship between the rates of the substance and the chemical reaction.
引用
收藏
页码:2703 / 2711
页数:9
相关论文
共 42 条
[11]  
Engel T., 2018, THERMODYNAMICS STAT
[12]   Developing the Chemist's Inner Coder: A MATLAB Tutorial on the Stochastic Simulation of a Pseudo-First-Order Reaction [J].
Fisher, Aidan A. E. .
JOURNAL OF CHEMICAL EDUCATION, 2020, 97 (05) :1476-1480
[13]  
Frost W., 1961, Journal of the American Chemical Society, V83, P4870, DOI DOI 10.1021/JA01484A048
[14]   Prelaboratory Practice with a Titration Simulation Program for Carbonate Mixtures [J].
Fu, Qiang ;
Fu, Shiyuan ;
Yang, Hui ;
Yu, Jing ;
Liu, Li .
JOURNAL OF CHEMICAL EDUCATION, 2024, 101 (03) :993-1001
[15]   A Refined Redox Titration Simulation Program for the Simple System [J].
Fu, Qiang ;
Liu, Li ;
Wang, Guofu ;
Yu, Jing ;
Fu, Shiyuan .
JOURNAL OF CHEMICAL EDUCATION, 2023, 100 (06) :2182-2189
[16]  
Halkides CJ, 2007, J CHEM EDUC, V84, P434
[17]   The o-phenylenediamine-horseradish peroxidase system:: Enzyme kinetics in the general chemistry laboratory [J].
Hamilton, TM ;
Dobie-Galuska, AA ;
Wietstock, SM .
JOURNAL OF CHEMICAL EDUCATION, 1999, 76 (05) :642-644
[18]   Kinetics of Carbaryl Hydrolysis: An Undergraduate Environmental Chemistry Laboratory [J].
Hawker, Darryl .
JOURNAL OF CHEMICAL EDUCATION, 2015, 92 (09) :1531-1535
[19]   Measurement of Enzyme Kinetics by Use of a Blood Glucometer: Hydrolysis of Sucrose and Lactose [J].
Heinzerling, Peter ;
Schrader, Frank ;
Schanze, Sascha .
JOURNAL OF CHEMICAL EDUCATION, 2012, 89 (12) :1582-1586
[20]   A Method for Teaching Enzyme Kinetics to Nonscience Majors [J].
Hinckley, Glen .
JOURNAL OF CHEMICAL EDUCATION, 2012, 89 (09) :1213-1214