Influences of NO3- Concentration and AC Interference on Corrosion Behavior and Mechanism of FeCoNi HEA in Simulated Saline-Alkali Soil Solution

The influences of NO3- concentration and AC density on corrosion resistance of FeCoNi high entropy alloy in simulated saline-alkali soil solution were studied via a series of measurements. Related results imply that the anticorrosion property of the HEA is significantly improved with the increase in NO3- concentration, particularly at high concentration of 0.1 mol/L, and the passive film covering the HEA becomes dense, intact and uniform. NO3- as a protective barrier is absorbed on the film surface, significantly inhibiting the pitting corrosion of the HEA. As AC density rises, the HEA surface status evolves from passivation to activated state, presenting a serious overall corrosion feature. The AC application facilitates the damage of passivation film grown on the HEA, resulting in a rapid increase in the number of flaws, which remarkedly decreases its resistance capacity against corrosion. Furthermore, under the combined influence of the two factors, the adverse effect of AC interference is obviously larger than the positive impact of NO3- on the corrosion resistance of the HEA at i(AC) of 50 A/m(2), causing plentiful defects within the passive film and severe corrosion of FeCoNi HEA.