Copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide and trimethylsilylazole derivatives

被引：0

作者：

Yuan, Qingbing ^{[1
,2
]}

Wu, Caiqiong ^{[1
]}

Bao, Yonghu ^{[1
]}

Huang, Zengming ^{[3
]}

Wang, Hua ^{[1
,2
]}

Wei, Yun ^{[1
]}

Wang, Shaowu ^{[3
]}

机构：

[1] Anhui Normal Univ, Coll Chem & Mat Sci, Key Lab Funct Mol Solids, Anhui Lab Mol Based Mat,Minist Educ, Wuhu 241002, Peoples R China

[2] Anhui Zhongtian New Mat Technol Co Ltd, Wuhu 241206, Anhui, Peoples R China

[3] Anhui Polytech Univ, Coll Chem & Environm Engn, Anhui Lab Funct Complexes Mat Chem & Applicat, Wuhu 241000, Anhui, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 51期

基金：

中国国家自然科学基金;

关键词：

ALKENES; STYRENES; AMINOOXYGENATION; AMINATION; ALKYNES; AZOLES; ACCESS;

D O I：

10.1039/d5cc01080b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper-catalyzed three-component radical aminoazolation of vinylarenes with N-fluorobenzenesulfonimide (NFSI) and trimethylsilylazole derivatives has been developed. This methodology provides an efficient and straightforward approach to generate various beta-sulfoamino azoles in good to excellent yields. The protocol features exclusive chemo- and regioselectivity, and excellent functional group tolerance under mild conditions.

引用

页码：9238 / 9241

页数：4

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