Prototype symmetric solid-state supercapacitor designed through Co3Fe4(PO4)6/MWCNT electrodes

被引:0
作者
Deshmukh, Tushar B. [1 ,2 ]
Agarwal, Akanksha [4 ]
Mendhe, Avinash C. [3 ]
Thosare, Mayur [2 ]
Sankapal, Babasaheb R. [2 ]
机构
[1] Ent 2 Energy Storage Pvt Ltd, Chennai 600056, Tamil Nadu, India
[2] Visvesvaraya Natl Inst Technol, Dept Phys, South Ambazari Rd, Nagpur 440010, Maharashtra, India
[3] Kyung Hee Univ, Dept Elect Engn, 1732 Deogyeong Daero, Yongin 17104, South Korea
[4] Dr Bhimrao Ambedkar Univ, Inst Basic Sci, Dept Phys, Khandari Campus, Agra 282002, India
关键词
Solid-state symmetric supercapacitor; MWCNT/Co3Fe4(PO4)6; Metal phosphates; Carbon nanotubes; THIN-FILMS; PERFORMANCE;
D O I
10.1016/j.cplett.2025.142070
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work presents a prototype solid-state symmetric supercapacitor (SSS) using cobalt iron phosphate-anchored multiwalled carbon nanotubes (MWCNT/Co3Fe4(PO4)6) with a polyvinyl alcohol-potassium hydroxide (PVAKOH) gel electrolyte. This advanced structure overcomes issues of the liquid electrolytes like leakage and degradation, enhancing mechanical resilience and longevity. The device exhibited a specific capacitance of 68.6 F g-1, with energy and power densities of 21.4 Wh kg-1 and 2147.8 W kg-1 at 1 mA cm-2. Notably, the device also retained 91 % capacitance over 2000 cycles, demonstrating superior electrochemical properties, mechanical adaptability, and potential for next-generation portable energy storage technologies.
引用
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页数:6
相关论文
共 36 条
[1]   Carbon Nanotube-Functionalized Surface-Assisted Growth of Cobalt Phosphate Nanodots: A Highly Stable and Bendable All-Solid-State Symmetric Supercapacitor [J].
Agarwal, Akanksha ;
Majumder, Sutripto ;
Sankapal, Babasaheb R. .
ENERGY & FUELS, 2022, 36 (11) :5953-5964
[2]   Ultrathin Cu2P2O7 nanoflakes on stainless steel substrate for flexible symmetric all-solid-state supercapacitors [J].
Agarwal, Akanksha ;
Sankapal, Babasaheb R. .
CHEMICAL ENGINEERING JOURNAL, 2021, 422 (422)
[3]   Amorphous, binder-free cobalt manganese phosphate cathodes prepared by SILAR method for asymmetric supercapacitors: Harnessing cationic synergy [J].
Belekar, Kuladip G. ;
Patil, Sumita S. ;
Bhosale, Shraddha B. ;
Kumbhar, Sambhaji S. ;
Jadhav, Ganesh D. ;
Parale, Vinayak G. ;
Lokhande, Chandrakant D. ;
Park, Hyung-Ho ;
Katkar, Pranav K. ;
Patil, Umakant M. .
SYNTHETIC METALS, 2025, 311
[4]   True Meaning of Pseudocapacitors and Their Performance Metrics: Asymmetric versus Hybrid Supercapacitors [J].
Chodankar, Nilesh R. ;
Pham, Hong Duc ;
Nanjundan, Ashok Kumar ;
Fernando, Joseph F. S. ;
Jayaramulu, Kolleboyina ;
Golberg, Dmitri ;
Han, Young-Kyu ;
Dubal, Deepak P. .
SMALL, 2020, 16 (37)
[5]   Blossoming of Multivalent Iron Phosphate Microplatelets Grown on Multiwall Carbon Nanotube Frameworks: Investigation of Supercapacitive Performance through Symmetric and Asymmetric Configurations [J].
Deshmukh, Tushar B. B. ;
Babar, Pravin ;
Sankapal, Babasaheb R. R. .
ENERGY & FUELS, 2023, 37 (15) :11406-11418
[6]  
Guo F., 2018, Supercapacitors-Theor
[7]  
Karade S.S., 2018, Chem. Eng., V6, P15072
[8]   Decoration of Ultrathin MoS2 Nanoflakes over MWCNTs: Enhanced Supercapacitive Performance through Electrode to Symmetric All-Solid-State Device [J].
Karade, Swapnil S. ;
Dubal, Deepak P. ;
Sankapal, Babasaheb R. .
CHEMISTRYSELECT, 2017, 2 (32) :10405-10412
[9]   Self-assembled 3D cobalt phosphate octahydrate architecture for supercapacitor electrodes [J].
Li, Haiyan ;
Yu, Hongwen ;
Zhai, Jiali ;
Sun, Lei ;
Yang, Hongjun ;
Xie, Songhai .
MATERIALS LETTERS, 2015, 152 :25-28
[10]   Metal (M = Co, Ni) phosphate based materials for high-performance supercapacitors [J].
Li, Xinran ;
Xiao, Xiao ;
Li, Qing ;
Wei, Jilei ;
Xue, Huaiguo ;
Pang, Huan .
INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (01) :11-28