Changes in Wood Plastic Composite Properties After Natural Weathering and Potential Microplastic Formation

Wood plastic composites (WPCs) have recently gained attention as alternatives to traditional wood materials for outdoor use, thanks to their enhanced moisture resistance and durability, which extends their service life. Discolouration as well as surface erosion has been observed during weathering for both WPCs with untreated and heat-treated wood. However, aspects such as changes in surface hydrophobicity, chemistry, and erosion in terms of microplastic formation have received less attention; this research aimed to evaluate these factors during natural weathering. Four types of WPC samples, consisting of 50% wood particles (untreated and heat-treated) and 50% polypropylene, were naturally weathered in Latvia for two years. The samples measured 240 mm x 240 mm x 5 mm. Results showed rapid colour changes, microcracks, and exposed wood particles, suggesting microplastic formation. ATR-FTIR analysis showed increased absorption at 1715 cm(-)(1) (carbonyl groups) and at 3410 cm-1 and 3460 cm-1, typical of wood, indicating chemical changes on the surface. These changes influenced surface hydrophobicity, roughness, and water penetration. In a relatively short exposure time, WPCs without proper additives undergo significant changes in their aesthetic and physical properties, leading to surface erosion and potential microplastic formation. This could challenge the perception of WPCs as environmentally friendly materials.