Insights into Operating Conditions on Electrocatalytic CO2 Reduction

被引：0

作者：

Zhu, Zhaozhao ^{[1
]}

Tang, Wu ^{[1
]}

Wang, Junjie ^{[1
]}

Zhao, Lei ^{[1
]}

Lin, Yingxi ^{[1
]}

Li, Zhao ^{[2
]}

Niu, Xiaobin ^{[1
]}

Chen, Jun Song ^{[1
,2
]}

Wu, Rui ^{[1
]}

机构：

[1] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 610054, Peoples R China

[2] Chengdu Univ, Inst Adv Study, Interdisciplinary Mat Res Ctr, Chengdu 610106, Peoples R China

来源：

ADVANCED ENERGY MATERIALS | 2025年 / 15卷 / 16期

基金：

中国国家自然科学基金;

关键词：

CO2; electroreduction; electrolyte; membrane electrode assembly; operating environment; ELECTROCHEMICAL REDUCTION; IONIC LIQUID; CARBON-DIOXIDE; MULTICARBON PRODUCTS; WATER TRANSPORT; HIGH-PRESSURE; CU ELECTRODE; ELECTROREDUCTION; CONVERSION; ENVIRONMENT;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrocatalytic CO2 reduction (CO2RR) is rapidly emerging as a promising sustainable strategy for transforming CO2 into valuable fuels and chemical feedstocks, a crucial step toward a carbon-neutral society. The efficiency, selectivity, and stability of CO2RR are heavily influenced by the chosen catalyst and the operating conditions used. Despite substantial advances in the development of catalysts, there is a scarcity of comprehensive reviews focusing on the influence of different operating environments on CO2RR performance. This review offers a detailed examination of internal and external environmental control strategies designed to enhance CO2RR efficiency. The fundamental reaction mechanisms through in situ and operational techniques, paired with theoretical analyses, are discussed while also identifying key challenges and future research directions in CO2RR technology. By delivering a comprehensive overview of the current state of the field, this review highlights the critical role of environmental control, mechanistic insights, and practical considerations needed for the successful commercialization of CO2RR technology.

引用

页数：20

共 201 条

[71] Manipulating the Hydrocarbon Selectivity of Copper Nanoparticles in CO2 Electroreduction by Process Conditions [J].

Kas, Recep ;

Kortlever, Ruud ;

Yilmaz, Hasan ;

Koper, Marc T. M. ;

Mul, Guido .

CHEMELECTROCHEM, 2015, 2 (03) :354-358

[72] Impact of Pulsed Electrochemical Reduction of CO2 on the Formation of C2+ Products over Cu [J].

Kim, Chanyeon ;

Weng, Lien-Chun ;

Bell, Alexis T. .

ACS CATALYSIS, 2020, 10 (21) :12403-12413

[73] Design principles for selective and economical CO2 electrolysis in acids [J].

Kim, Jaehoon ;

Ha, Tae Hyeon ;

Kim, Junehyeok ;

Jeong, Gyoung Hwa ;

Kim, Sang Ouk ;

Chung, Wonsuk ;

Roh, Kosan ;

Lee, Jay H. ;

Oh, Jihun .

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2023, 339

[74] Controlled Selectivity of CO2 Reduction on Copper by Pulsing the Electrochemical Potential [J].

Kimura, Kevin W. ;

Fritz, Kevin E. ;

Kim, Jiyoon ;

Suntivich, Jin ;

Abruna, Hector D. ;

Hanrath, Tobias .

CHEMSUSCHEM, 2018, 11 (11) :1781-1786

[75] Magnetic fields enhance mass transport during electrocatalytic reduction of CO2 [J].

Kodaimati, Mohamad S. ;

Gao, Rui ;

Root, Samuel E. ;

Whitesides, George M. .

CHEM CATALYSIS, 2022, 2 (04) :797-815

[76] Interrogation of Oxidative Pulsed Methods for the Stabilization of Copper Electrodes for CO2 Electrolysis [J].

Kok, Jesse ;

de Ruiter, Jim ;

van der Stam, Ward ;

Burdyny, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (28) :19509-19520

[77] Experimental Demonstration of Topological Catalysis for CO2 Electroreduction [J].

Kong, Xiangdong ;

Liu, Zhao ;

Geng, Zhigang ;

Zhang, An ;

Guo, Ziyang ;

Cui, Shengtao ;

Xia, Chuan ;

Tan, Shijing ;

Zhou, Shiming ;

Wang, Zhengfei ;

Zeng, Jie .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (10) :6536-6543

[78] Co-based molecular catalysts for efficient CO2 reduction via regulating spin states [J].

Kong, Xiangdong ;

Ke, Jingwen ;

Wang, Zhiqiang ;

Liu, Yan ;

Wang, Yibo ;

Zhou, Weiran ;

Yang, Zhengwu ;

Yan, Wensheng ;

Geng, Zhigang ;

Zeng, Jie .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 290

[79] Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction [J].

Kumar, Bijandra ;

Asadi, Mohammad ;

Pisasale, Davide ;

Sinha-Ray, Suman ;

Rosen, Brian A. ;

Haasch, Richard ;

Abiade, Jeremiah ;

Yarin, Alexander L. ;

Salehi-Khojin, Amin .

NATURE COMMUNICATIONS, 2013, 4

[80] New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO2 on a Silver Electrode [J].

Lau, Genevieve P. S. ;

Schreier, Marcel ;

Vasilyev, Drnitry ;

Scopelliti, Rosario ;

Gratzel, Michael ;

Dyson, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (25) :7820-7823

← 3 4 5 6 7 8 9 10 11 12 →