Insights into Operating Conditions on Electrocatalytic CO2 Reduction

被引：0

作者：

Zhu, Zhaozhao ^{[1
]}

Tang, Wu ^{[1
]}

Wang, Junjie ^{[1
]}

Zhao, Lei ^{[1
]}

Lin, Yingxi ^{[1
]}

Li, Zhao ^{[2
]}

Niu, Xiaobin ^{[1
]}

Chen, Jun Song ^{[1
,2
]}

Wu, Rui ^{[1
]}

机构：

[1] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 610054, Peoples R China

[2] Chengdu Univ, Inst Adv Study, Interdisciplinary Mat Res Ctr, Chengdu 610106, Peoples R China

来源：

ADVANCED ENERGY MATERIALS | 2025年 / 15卷 / 16期

基金：

中国国家自然科学基金;

关键词：

CO2; electroreduction; electrolyte; membrane electrode assembly; operating environment; ELECTROCHEMICAL REDUCTION; IONIC LIQUID; CARBON-DIOXIDE; MULTICARBON PRODUCTS; WATER TRANSPORT; HIGH-PRESSURE; CU ELECTRODE; ELECTROREDUCTION; CONVERSION; ENVIRONMENT;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrocatalytic CO2 reduction (CO2RR) is rapidly emerging as a promising sustainable strategy for transforming CO2 into valuable fuels and chemical feedstocks, a crucial step toward a carbon-neutral society. The efficiency, selectivity, and stability of CO2RR are heavily influenced by the chosen catalyst and the operating conditions used. Despite substantial advances in the development of catalysts, there is a scarcity of comprehensive reviews focusing on the influence of different operating environments on CO2RR performance. This review offers a detailed examination of internal and external environmental control strategies designed to enhance CO2RR efficiency. The fundamental reaction mechanisms through in situ and operational techniques, paired with theoretical analyses, are discussed while also identifying key challenges and future research directions in CO2RR technology. By delivering a comprehensive overview of the current state of the field, this review highlights the critical role of environmental control, mechanistic insights, and practical considerations needed for the successful commercialization of CO2RR technology.

引用

页数：20

共 201 条

[1] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Munro, HL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011

[2] Insertion of MXene-Based Materials into Cu-Pd 3D Aerogels for Electroreduction of CO2 to Formate [J].

Abdinejad, Maryam ;

Subramanian, Siddhartha ;

Motlagh, Mozhgan Khorasani ;

Noroozifar, Meissam ;

Duangdangchote, Salatan ;

Neporozhnii, Ihor ;

Ripepi, Davide ;

Pinto, Donato ;

Li, Mengran ;

Tang, Keith ;

Middelkoop, Joost ;

Urakawa, Atsushi ;

Voznyy, Oleksandr ;

Kraatz, Heinz-Bernhard ;

Burdyny, Thomas .

ADVANCED ENERGY MATERIALS, 2023, 13 (19)

[3] Electrochemical CO2 reduction to CO facilitated by MDEA-based deep eutectic solvent in aqueous solution [J].

Ahmad, Naveed ;

Wang, Xiaoxiao ;

Sun, Peixu ;

Chen, Ying ;

Rehman, Fahad ;

Xu, Jian ;

Xu, Xia .

RENEWABLE ENERGY, 2021, 177 :23-33

[4] Biocompatible Nanoclusters with High Heating Efficiency for Systemically Delivered Magnetic Hyperthermia [J].

Albarqi, Hassan A. ;

Wong, Leon H. ;

Schumann, Canan ;

Sabei, Fahad Y. ;

Korzun, Tetiana ;

Li, Xiaoning ;

Hansen, Mikkel N. ;

Dhagat, Pallavi ;

Moses, Abraham S. ;

Taratula, Olena ;

Taratula, Oleh .

ACS NANO, 2019, 13 (06) :6383-6395

[5] MECHANISM AND KINETIC CHARACTERISTICS OF THE ELECTROCHEMICAL REDUCTION OF CARBON-DIOXIDE IN MEDIA OF LOW PROTON AVAILABILITY [J].

AMATORE, C ;

SAVEANT, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) :5021-5023

[6] The role of in situ generated morphological motifs and Cu(i) species in C2+ product selectivity during CO2 pulsed electroreduction [J].

Aran-Ais, Rosa M. ;

Scholten, Fabian ;

Kunze, Sebastian ;

Rizo, Ruben ;

Roldan Cuenya, Beatriz .

NATURE ENERGY, 2020, 5 (04) :317-325

[7] Directing the Outcome of CO2 Reduction at Bismuth Cathodes Using Varied Ionic Liquid Promoters [J].

Atifi, Abderrahman ;

Boyce, David W. ;

DiMeglio, John L. ;

Rosenthal, Joel .

ACS CATALYSIS, 2018, 8 (04) :2857-2863

[8] High-Performance Porous Ionic Liquids for Low-Pressure CO2 Capture** [J].

Avila, Jocasta ;

Lepre, L. Fernando ;

Santini, Catherine C. ;

Tiano, Martin ;

Denis-Quanquin, Sandrine ;

Chung Szeto, Kai ;

Padua, Agilio A. H. ;

Costa Gomes, Margarida .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (23) :12876-12882

[9] Accelerating the Reaction Kinetics of CO2 Reduction to Multi-Carbon Products by Synergistic Effect between Cation and Aprotic Solvent on Copper Electrodes [J].

Bai, Xiaowan ;

Chen, Chaojie ;

Zhao, Xunhua ;

Zhang, Yehui ;

Zheng, Yao ;

Jiao, Yan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (09)

[10] When Flooding Is Not Catastrophic-Woven Gas Diffusion Electrodes Enable Stable CO2 Electrolysis [J].

Baumgartner, Lorenz M. ;

Koopman, Christel I. ;

Forner-Cuenca, Antoni ;

Vermaas, David A. .

ACS APPLIED ENERGY MATERIALS, 2022, 5 (12) :15125-15135

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