Electron-induced dissociation of HFO1234ze: dissociative electron attachment and dissociative ionization

被引:0
作者
Lyshchuk, Hlib [1 ,2 ]
van Rijn, Marnik Metting [3 ]
Paul, Anirban [1 ]
Kocisek, Jaroslav [1 ]
Rankovic, Milos [1 ]
Nag, Pamir [1 ]
Fedor, Juraj [1 ]
机构
[1] Czech Acad Sci, J Heyrovsky Inst Phys Chem, Dolejskova 3, Prague 18223, Czech Republic
[2] Univ Chem & Technol, Dept Phys Chem, Tech 5, Prague 16628, Czech Republic
[3] Swiss Fed Inst Technol, Inst Power Syst & High Voltage Technol, Phys Str 3, CH-8092 Zurich, Switzerland
基金
瑞士国家科学基金会;
关键词
attachment; dissociative; ionization; resonances; CROSS-SECTIONS; NEGATIVE-IONS; IMPACT; SCATTERING; ATOMS;
D O I
10.1088/1402-4896/adcb77
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We studied free electron collision-induced fragmentation of HFO1234ze(E) (C3H2F4). The motivation of the present study is to assess the possibility of using this gas in resistive plate chamber detectors and for the interest in its electron-induced decomposition. Two electron-collision setups, which complement each other, are used. Additionally, the interpretation of the data is supported by quantum chemical calculations. We provide absolute partial cross sections both for the dissociative electron attachment and for the positive ionization. We also report the ionization energy of HFO1234ze(E) and the appearance energies of selected fragments. A surprising finding of the current study is that the dominant anionic fragment from the dissociative electron attachment is the bifluoride anion [F-H-F](-).
引用
收藏
页数:11
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