We studied free electron collision-induced fragmentation of HFO1234ze(E) (C3H2F4). The motivation of the present study is to assess the possibility of using this gas in resistive plate chamber detectors and for the interest in its electron-induced decomposition. Two electron-collision setups, which complement each other, are used. Additionally, the interpretation of the data is supported by quantum chemical calculations. We provide absolute partial cross sections both for the dissociative electron attachment and for the positive ionization. We also report the ionization energy of HFO1234ze(E) and the appearance energies of selected fragments. A surprising finding of the current study is that the dominant anionic fragment from the dissociative electron attachment is the bifluoride anion [F-H-F](-).
机构:
Emory Univ, Dept Chem, Atlanta, GA 30322 USA
Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USA
Yale Univ, Dept Chem, New Haven, CT 06520 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Yu, Qi
;
Lewis, Nicholas H. C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Lewis, Nicholas H. C.
;
Carpenter, William B.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Carpenter, William B.
;
Bowman, Joel M.
论文数: 0引用数: 0
h-index: 0
机构:
Emory Univ, Dept Chem, Atlanta, GA 30322 USA
Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Bowman, Joel M.
;
Tokmakoff, Andrei
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
机构:
Emory Univ, Dept Chem, Atlanta, GA 30322 USA
Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USA
Yale Univ, Dept Chem, New Haven, CT 06520 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Yu, Qi
;
Lewis, Nicholas H. C.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Lewis, Nicholas H. C.
;
Carpenter, William B.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Carpenter, William B.
;
Bowman, Joel M.
论文数: 0引用数: 0
h-index: 0
机构:
Emory Univ, Dept Chem, Atlanta, GA 30322 USA
Emory Univ, Cherry L Emerson Ctr Sci Computat, Atlanta, GA 30322 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Bowman, Joel M.
;
Tokmakoff, Andrei
论文数: 0引用数: 0
h-index: 0
机构:
Univ Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA
Univ Chicago, James Franck Inst, Chicago, IL 60637 USAUniv Chicago, Dept Chem, Inst Biophys Dynam, Chicago, IL 60637 USA