Design of microwave-supported activated carbon derived from lentil processing residual for efficient heavy metals adsorption and supercapacitor applications
Lentil processing residual;
Activated carbon;
Adsorption;
Heavy metals;
Supercapacitor;
Energy storage;
AQUEOUS-SOLUTION;
CHEMICAL ACTIVATION;
METHYLENE-BLUE;
POROUS CARBON;
REMOVAL;
WASTE;
SHELL;
COBALT;
PERFORMANCE;
PYROLYSIS;
D O I:
10.1016/j.talanta.2025.128068
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
In this study, the re-evaluation of lentil processing residual (LPR) in the form of microwave-supported activated carbon (LPRAC) and its use as a potential sorbent for the removal of Co2+ and Mn2+ heavy metals and also as a supercapacitor electrode material is presented. The differential thermogravimetric analysis (TG-DTA), BrunauerEmmett-Teller (BET) analysis, scanning electron microscope (SEM), energy dispersive X-ray (EDX) spectroscopy, Fourier-transform infrared spectroscopy (FTIR), and cyclic voltammetry methods were employed to analyze thermal feature, specific surface area, surface morphology, surface functional groups, and electrochemical behavior, respectively. During adsorption, the maximum uptake capacities were 145.5 and 300.56 mg/g for Co2+ and Mn2+, respectively. In a supercapacitor, the LPRAC electrode has a capacitance of 187.65 F/g and a capacitance retention of 92 % at 0.04 A/g after 1000 cycles. The superior adsorption and electrochemical performance of LPRAC indicates that this material can be a strong candidate for both wastewater treatment and energy storage applications.
机构:
Alfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlTowyan, Layan
;
AlSagabi, Sultan
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机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlSagabi, Sultan
;
AlAjyan, Turki
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h-index: 0
机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlAjyan, Turki
;
AlSulami, Khalifa
论文数: 0引用数: 0
h-index: 0
机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlSulami, Khalifa
;
Goumri-Said, Souraya
论文数: 0引用数: 0
h-index: 0
机构:
Alfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
机构:
Covenant Univ, Dept Chem Engn, Km 10 Idiroko Rd,Canaan Land, Ota, Nigeria
Univ Port Harcourt, Inst Petr Studies, East West Rd,PMB 2, Port Harcourt, NigeriaLagos State Univ, Dept Chem & Polymer Engn, Lagos, Nigeria
机构:
Alfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlTowyan, Layan
;
AlSagabi, Sultan
论文数: 0引用数: 0
h-index: 0
机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlSagabi, Sultan
;
AlAjyan, Turki
论文数: 0引用数: 0
h-index: 0
机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlAjyan, Turki
;
AlSulami, Khalifa
论文数: 0引用数: 0
h-index: 0
机构:
King Abdulaziz City Sci & Technol, POB 6086, Riyadh 11442, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
AlSulami, Khalifa
;
Goumri-Said, Souraya
论文数: 0引用数: 0
h-index: 0
机构:
Alfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi ArabiaAlfaisal Univ, Coll Sci & Gen Studies, Phys Dept, POB 50927, Riyadh 11533, Saudi Arabia
机构:
Covenant Univ, Dept Chem Engn, Km 10 Idiroko Rd,Canaan Land, Ota, Nigeria
Univ Port Harcourt, Inst Petr Studies, East West Rd,PMB 2, Port Harcourt, NigeriaLagos State Univ, Dept Chem & Polymer Engn, Lagos, Nigeria