Photocatalysis Decomposition of Hydrogen Sulfide (H2S) in Ethanolamine Solution Using CuO/ZnO/ZnFe2O4

被引:0
作者
Rania Farouq [1 ]
Agid Remadan [2 ]
Nasser A. M. Barakat [3 ]
Haidar Saify Nabiabad [4 ]
A. M. Dorgham [1 ]
机构
[1] Tanta Higher Institute of Engineering and Technology,Chemical Engineering Department
[2] Institute of Science and Modern Technology,Chemical Engineering Department
[3] Minia University,Department of Biotechnology
[4] Bu-Ali Sina University,undefined
关键词
Photocatalysis; CuO/ZnO/ZnFe; O; H; S splitting; Aqueous media; H effect; Ethanolamine;
D O I
10.1007/s10562-025-05058-w
中图分类号
学科分类号
摘要
Refineries produce large amounts of H2S, which can be decomposed in the well-known Claus process to turn into sulfur and water. Due to the expensive chemical process and additional serious environmental issues, it causes, this approach is not commercially viable. Therefore, herein we have shown how to degrade toxic H2S using phocatalysis, a green, non-conventional energy source that is also environmentally friendly. In this research, laboratory experiments were conducted on a sample of diethanolamine solution (DEA) loaded with H2S from gas associated with oil at “the Swedish Gas Plant” in Syria. We have investigated the use of nanostructured CuO/ZnO/ZnFe2O4 photocatalyst for the degradation of H2S. The microstructure of the newly prepared CuO/ZnO/ ZnFe2O4 was examined using X-ray diffraction (XRD), Energy-Dispersive X-ray Spectroscopy (EDX or EDS), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The effect of pH and catalyst dosage was investigated on the photocatalyst performance.
引用
收藏
相关论文
共 50 条
  • [41] Fabrication of magnetic and recyclable In2S3/ZnFe2O4 nanocomposites for visible light photocatalytic activity enhancement
    Zhao, Wenye
    Huang, Yun
    Su, Chunyan
    Gao, Yepen
    Tian, Wenhui
    Yang, Xudong
    MATERIALS RESEARCH EXPRESS, 2020, 7 (01)
  • [42] ZnO/ZnFe2O4 Janus Hollow Nanofibers with Magnetic Separability for Photocatalytic Degradation of Water-Soluble Organic Dyes
    Liu, Haiyang
    Han, Chaohan
    Shao, Changlu
    Yang, Shu
    Li, Xiaowei
    Li, Bing
    Li, Xinghua
    Ma, Jiangang
    Liu, Yichun
    ACS APPLIED NANO MATERIALS, 2019, 2 (08): : 4879 - 4890
  • [43] Surface Modification of ZnO Nanowires with CuO: A Tool to Realize Highly-Sensitive H2S Sensor
    C. P. Goyal
    D. Goyal
    N. S. Ramgir
    M. Navaneethan
    Y. Hayakawa
    C. Muthamizhchelvan
    H. Ikeda
    S. Ponnusamy
    Physics of the Solid State, 2021, 63 : 460 - 467
  • [44] Pyroelectric field drived photocatalysis by ZnFe2O4/NaNbO3 heterojunction for dye degradation through integration of solar and thermal energy
    Zhou, Di
    Zhou, Xiaoju
    Hu, Zhenglong
    Zheng, Lili
    Tian, Yu
    Tu, Yafang
    Hua, Chunbo
    Xue, Li
    Xiong, Juan
    ARABIAN JOURNAL OF CHEMISTRY, 2024, 17 (11)
  • [45] Study on the Degradation of Chlortetracycline Hydrochloride in Mariculture Wastewater by Zn0.75Mn0.75Fe1.5O4/ZnFe2O4/ZnO Photocatalyst
    Jiayuan Fu
    Xiaocai Yu
    Zejun Li
    Yongxia Zhang
    Wanting Zhu
    Jinghua Liu
    Water, Air, & Soil Pollution, 2021, 232
  • [46] Selective oxidation of H2S to ammonium thiosulfate and elemental sulfur using mixtures of V-Bi-O and Sb2O4
    Bong-Kuk Kim
    Byung-Ha Hwang
    Hwa-Soo Lee
    Hee-Chul Woo
    Dae-Won Park
    Korean Journal of Chemical Engineering, 2004, 21 : 104 - 109
  • [47] Green and efficient synthesis of 2, 3-dihydroquinazolin-4(1H)-ones in aqueous medium using ZnFe2O4 catalyst under microwave irradiation
    Balaji D. Rupnar
    Tejswini R. Kachave
    Pramod D. Jawale
    Suresh U. Shisodia
    Rajendra P. Pawar
    Journal of the Iranian Chemical Society, 2017, 14 : 1853 - 1858
  • [48] Heterostructured ZnFe2O4/Fe2TiO5/TiO2 Composite Nanotube Arrays with an Improved Photocatalysis Degradation Efficiency Under Simulated Sunlight Irradiation
    Xiong, Kun
    Wang, Kunzhou
    Chen, Lin
    Wang, Xinqing
    Fan, Qingbo
    Courtois, Jeremie
    Liu, Yuliang
    Tuo, Xianguo
    Yan, Minhao
    NANO-MICRO LETTERS, 2018, 10 (01) : 1 - 11
  • [49] Heterostructured ZnFe2O4/Fe2TiO5/TiO2 Composite Nanotube Arrays with an Improved Photocatalysis Degradation Efficiency Under Simulated Sunlight Irradiation
    Kun Xiong
    Kunzhou Wang
    Lin Chen
    Xinqing Wang
    Qingbo Fan
    Jérémie Courtois
    Yuliang Liu
    Xianguo Tuo
    Minhao Yan
    Nano-Micro Letters, 2018, (01) : 158 - 168
  • [50] Heterostructured ZnFe2O4/Fe2TiO5/TiO2 Composite Nanotube Arrays with an Improved Photocatalysis Degradation Efficiency Under Simulated Sunlight Irradiation
    Kun Xiong
    Kunzhou Wang
    Lin Chen
    Xinqing Wang
    Qingbo Fan
    Jérémie Courtois
    Yuliang Liu
    Xianguo Tuo
    Minhao Yan
    Nano-Micro Letters, 2018, 10