Butylammonium Hexachlorostannate for Lithium-Ion Batteries: An Experimental Application

被引:0
作者
Romero-Contreras, Alfredo [1 ]
Gonzalez-Juarez, Edgar [1 ]
Briones-Martinez, Ricardo [1 ]
Sanchez-Cervantes, Eduardo M. [1 ]
机构
[1] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, San Nicolas De Los Garza, Mexico
关键词
Lithium-ion batteries; electrodes; hexachlorostannates; energy storage; TRANSITIONS; PEROVSKITES;
D O I
10.1007/s11664-025-11916-5
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this study, we investigate the application of butylammonium hexachlorostannate (BAHCS) as a novel material for enhancing the performance of lithium-ion batteries (LIBs). BAHCS, a metal halide perovskite-related compound, is expected to exhibit potential electrochemical properties due to its hybrid organic-inorganic structure. We synthesized and characterized BAHCS, evaluating its potential as an electrode material in LIBs. Electrochemical testing demonstrated that BAHCS possesses a moderate specific capacity (around 100 mAh g-1) and good capacity retention and cycling stability. This study highlights the promise of BAHCS as a functional material in next-generation LIBs, providing a pathway for the development of organic-inorganic energy storage devices. Our findings suggest that further optimization of BAHCS-based materials could lead to significant advancements in LIB technology, indicating that incorporation of new inorganic cations in perovskite materials might improve the lithium insertion-extraction process in the cathode.
引用
收藏
页码:4597 / 4605
页数:9
相关论文
共 29 条
[1]   Organic-inorganic hybrid materials and architectures in optoelectronic devices: Recent advancements [J].
Arya, M. ;
Heera, S. ;
Meenu, P. ;
Deepa, K. G. .
CHEMPHYSMATER, 2024, 3 (03) :252-272
[2]  
Bijvoet JM, 1926, P K AKAD WET-AMSTERD, V29, P1286
[3]   Electrochemical Impedance Spectroscopy of Metal Oxide Electrodes for Energy Applications [J].
Bredar, Alexandria R. C. ;
Chown, Amanda L. ;
Burton, Andricus R. ;
Farnum, Byron H. .
ACS APPLIED ENERGY MATERIALS, 2020, 3 (01) :66-98
[4]   STUDY OF NEW ALKYLAMMONIUM HEXACHLOROSTANNATES AND THEIR PHASE-TRANSITIONS BY DIFFERENTIAL SCANNING CALORIMETRY AND INFRARED-SPECTROSCOPY [J].
CERMAK, M ;
FUITH, A ;
VANEK, P ;
SILHA, J ;
MALKOVA, Z .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1994, 182 (02) :289-294
[5]   Mechanisms of Lithium Intercalation and Conversion Processes in Organic-Inorganic Halide Perovskites [J].
Dawson, James A. ;
Naylor, Andrew J. ;
Eames, Christopher ;
Roberts, Matthew ;
Zhang, Wei ;
Snaith, Henry J. ;
Bruce, Peter G. ;
Islam, M. Saiful .
ACS ENERGY LETTERS, 2017, 2 (08) :1818-1824
[6]   Structural differential scanning calorimetric and spectroscopic studies of the new two-dimensional compound (C4H9NH3)(2)SnCl6 [J].
Elleuch, H ;
Kamoun, M ;
Daoud, A ;
Jouini, T .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1996, 157 (01) :3-9
[7]   Perovskite light-emitting diodes [J].
Fakharuddin, Azhar ;
Gangishetty, Mahesh K. ;
Abdi-Jalebi, Mojtaba ;
Chin, Sang-Hyun ;
Yusoff, Abd Rashid bin Mohd ;
Congreve, Daniel N. ;
Tress, Wolfgang ;
Deschler, Felix ;
Vasilopoulou, Maria ;
Bolink, Henk J. .
NATURE ELECTRONICS, 2022, 5 (04) :203-216
[8]   Formamidinium Perovskitizers and Aromatic Spacers Synergistically Building Bilayer Dion-Jacobson Perovskite Photoelectric Bulk Crystals [J].
Fu, Dongying ;
Hou, Zuoming ;
He, Yueyue ;
Wu, Haodi ;
Wu, Shichao ;
Zhang, Yi ;
Niu, Guangda ;
Zhang, Xian-Ming .
ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (09) :11690-11698
[9]   2D homologous organic-inorganic hybrids as light-absorbers for planer and nanorod-based perovskite solar cells [J].
Gan, Xiaoyan ;
Wang, Ou ;
Liu, Keyong ;
Du, Xiangjun ;
Guo, Liling ;
Liu, Hanxing .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 162 :93-102
[10]   High-Performance All-Inorganic Architecture Perovskite Light-Emitting Diodes Based on Tens-of-Nanometers-Sized CsPbBr3 Emitters in a Carrier-Confined Heterostructure [J].
Gong, Xinquan ;
Hao, Xiaoming ;
Si, Junjie ;
Deng, Yunzhou ;
An, Kai ;
Hu, Qianqing ;
Cai, Qiuting ;
Gao, Yun ;
Ke, You ;
Wang, Nana ;
Du, Zhuopeng ;
Cai, Muzhi ;
Ye, Zhizhen ;
Dai, Xingliang ;
Liu, Zugang .
ACS NANO, 2024, 18 (12) :8673-8682