The kinetics and mechanisms of using cationic surfactants to reduce the dissolution of clay minerals

被引：0

作者：

Li, Jie ^{[1
]}

Guo, Yuen ^{[2
]}

Niu, Zhixiang ^{[1
]}

Li, Na ^{[3
]}

Cao, Yanling ^{[1
]}

Yin, Haishun ^{[1
]}

Jin, Lijie ^{[4
]}

Sun, Guoming ^{[1
]}

Guo, Li ^{[1
]}

Li, Chongying ^{[2
]}

机构：

[1] 1 Geol Team Shandong Prov Bur Geol & Mineral Resou, Jinan, Peoples R China

[2] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, Chengdu, Peoples R China

[3] Chengdu Univ Technol, Energy Coll, Chengdu, Peoples R China

[4] Jinan Petrochem Design Inst, Jinan, Peoples R China

来源：

CLAY MINERALS | 2025年

关键词：

Cationic surfactants; dissolution kinetics; kaolinite; modification; surface control; PRECIPITATION KINETICS; KAOLINITE DISSOLUTION; PH; TEMPERATURE; ACTIVATION; BEHAVIOR; ACID;

D O I：

10.1180/clm.2025.5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dissolution kinetics occurring on clay minerals are influenced by various factors, including pH, temperature and mineral lattice structure. However, the influence of the surfactant is rarely studied. In the present work, cationic surfactants were investigated in terms of the dissolution of clay minerals in acidic environments. Kaolinite was selected as the representative clay mineral. The cationic surfactant inhibited the dissolution of clay minerals because it limited the attack of H+ on the kaolinite surface and then inhibited the dissolution of kaolinite by modifying the hydrophilicity of the kaolinite surface towards hydrophobicity. The inhibition ability of the surfactant might be related to its molecular structure and the type of acid used in dissolution experiments.

引用

页数：10

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