Application of a copper complex supported on magnetic nanoparticles loaded on SBA-15 for Suzuki reaction under green and mild conditions

被引:0
作者
Alfaifi, Amani H. [1 ]
Almutib, Eman [1 ]
Algethami, Norah [1 ]
Jain, Vicky [2 ]
Roopashree, R. [3 ]
Kashyap, Aditya [4 ]
Jayabalan, Karthikeyan [5 ]
Ray, Subhashree [6 ]
机构
[1] Taif Univ, Coll Sci, Dept Phys, Taif 21944, Saudi Arabia
[2] Marwadi Univ, Res Ctr, Fac Sci, Dept Chem, Rajkot 360003, Gujarat, India
[3] JAIN, Sch Sci, Dept Chem & Biochem, Bangalore, Karnataka, India
[4] Chitkara Univ, Inst Engn & Technol, Ctr Res Impact & Outcome, Rajpura 140401, Punjab, India
[5] Sathyabama Inst Sci & Technol, Dept Chem, Chennai, Tamil Nadu, India
[6] Siksha OAnusandhan, IMS & SUM Hosp, Dept Biochem, Bhubaneswar 751003, Orissa, India
关键词
Copper; Magnetic nanoparticle; SBA-15; Support; Suzuki; C-C; CATALYST; EFFICIENT; MIYAURA; NICKEL;
D O I
10.1007/s11164-025-05580-x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the present work, we reported a copper complex immobilized onto magnetic SBA-15 nanoparticles (Fe3O4/SBA-15) as a magnetic nanocatalyst. The designed catalyst was authenticated using the following techniques: FT-IR, XRD, BET, TEM, TGA, EDS, VSM, and ICP-OES. Then, its catalytic performance was studied in the Suzuki cross-coupling reaction. The influences of different factors like solvent type, reaction time, reaction temperature, base type, and catalyst amount on the reaction efficiency were examined in detail. The aforesaid magnetic catalyst was effectively catalyzed the Suzuki cross-coupling reaction of arylboronic acids and various aryl halides at room temperature in water as cheap and green media. Furthermore, the catalyst maintained consistent activity over six cycles without any significant decline in performance. Besides, its magnetic feature made it easy to recover and reuse. Interestingly, the developed catalyst exhibited better performance than most of the heterogeneous Cu-based catalysts reported previously.
引用
收藏
页码:2897 / 2916
页数:20
相关论文
共 35 条
[1]   Highly Active Fe3O4@SBA-15@NHC-Pd Catalyst for Suzuki-Miyaura Cross-Coupling Reaction [J].
Akkoc, Mitat ;
Bugday, Nesrin ;
Altin, Serdar ;
ozdemir, Ismail ;
Yasar, Sedat .
CATALYSIS LETTERS, 2022, 152 (06) :1621-1638
[2]   Fe3O4@mesoporous SBA-15: A magnetically recoverable catalyst for photodegradation of malachite green [J].
Aliyan, Hamid ;
Fazaeli, Razieh ;
Jalilian, Rahil .
APPLIED SURFACE SCIENCE, 2013, 276 :147-153
[3]   Copper (II) Schiff base-graphene oxide composite as an efficient catalyst for Suzuki-Miyaura reaction [J].
Ansari, Rasheeda M. ;
Bhat, Badekai Ramachandra .
CHEMICAL PHYSICS, 2019, 517 :155-160
[4]   Copper complex with N-,O- architecture grafted graphene oxide nanosheet as a heterogeneous catalyst for Suzuki cross coupling reaction [J].
Anuma, Saroja ;
Mishra, Praveen ;
Bhat, Badekai Ramachandra .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2019, 95 :643-651
[5]   MCM-41 supported 2-aminothiophenol/Cu complex as a sustainable nanocatalyst for Suzuki coupling reaction [J].
Bibak, Sepideh ;
Marjani, Ahmad Poursattar ;
Aslaheh, Hamideh Sarreshtehdar .
SCIENTIFIC REPORTS, 2024, 14 (01)
[6]   Schiff bases and their metal Complexes: A review on the history, synthesis, and applications [J].
Boulechfar, Cherifa ;
Ferkous, Hana ;
Delimi, Amel ;
Djedouani, Amel ;
Kahlouche, Abdesalem ;
Boublia, Abir ;
Darwish, Ahmad S. ;
Lemaoui, Tarek ;
Verma, Rajesh ;
Benguerba, Yacine .
INORGANIC CHEMISTRY COMMUNICATIONS, 2023, 150
[7]   Mesoporous Silica SBA-15 Supported Pt-Ga Nanoalloys as an Active and Stable Catalyst for Propane Dehydrogenation [J].
Chen, Qiao ;
Deng, Lidan ;
Wu, Zewei ;
Wang, Fang ;
Jiang, Xingmao .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (23) :7799-7809
[8]   The effect of Lewis acidity of tin loading siliceous MCM-41 on glucose conversion into 5-hydroxymethylfurfural [J].
Fang, Juan ;
Dong, Hao ;
Xu, Haimei .
RENEWABLE ENERGY, 2023, 218
[9]   A novel COF-based Cu heterogeneous catalyst for a green Suzuki cross-coupling reaction under mild conditions [J].
Feng, Hui-Jun ;
Sun, Xue ;
Wang, Jun-Wen .
NEW JOURNAL OF CHEMISTRY, 2023, 47 (06) :3104-3111
[10]   Copper-Schiff base alumoxane: a new and reusable mesoporous nano catalyst for Suzuki-Miyaura and Stille C-C cross-coupling reactions [J].
Ghorbani-Choghamarani, Arash ;
Derakhshan, Ali Ashraf ;
Hajjami, Maryam ;
Rajabi, Laleh .
RSC ADVANCES, 2016, 6 (97) :94314-94324