Energy density comparable with Li-ion batteries from aqueous supercapatteries of PANI/V2O5/SnO2 nanocomposite and its green electrolytes

被引:0
作者
Viswanathan, Aranganathan [1 ]
Ramesh, Theertha Premalatha [1 ]
Naik, Megha [1 ]
Shetty, Adka Nityananda [1 ]
机构
[1] Natl Inst Technol Karnataka, Dept Chem, Mangalore 575025, India
来源
NEXT MATERIALS | 2025年 / 8卷
关键词
Polyaniline; Sulphuric acid; Byproduct electrolyte; Supercapattery; Energy density; Vanadium pentoxide; OXIDE; SUPERCAPACITOR; SPECTROSCOPY; PERFORMANCE; COMPOSITE; ELECTRODEPOSITION; OXIDATION;
D O I
10.1016/j.nxmate.2025.100622; 10.1016/j.nxmate.2025.100622
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The PANI53.85 %: V2O534.62 %: SnO211.53 % (PVS) ternary nanocomposite synthesized by insitu synthesis as supercapattery electrode material has exhibited energy density (E) equivalent to that of Li-ion batteries as the PVS furnishes an impressive E of 114.13 W h kg-1 with a high power density (P) of 2.400 kW kg-1 at 2 A g-1 in real 2 EL-supercapattery cell set up with low potential window (1.2 V) provided by 1 M H2SO4. The energy storage performance resulted by PVS is, a specific capacity (Q) of 684.8 C g-1, at 2 A g-1. The PVS is robust to withstand its energy storage characters up to 13600 cycles at 0.4 V s-1. The Li-ion supercapattery device of PVS made with a green electrolyte exhibited a Q of 672.0 C g-1, E of 112.0 W h kg-1 and P of 1.200 kW kg-1 at 1 A g-1 .
引用
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页数:12
相关论文
共 38 条
[21]   Glycol assisted synthesis of graphene- MnO2-polyaniline ternary composites for high performance supercapacitor electrodes [J].
Mu, Bin ;
Zhang, Wenbo ;
Shao, Shijun ;
Wang, Aiqin .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (17) :7872-7880
[22]  
O. Energy, 2018, OXIS ENERGY Progresses its Lithium Sulfur (Li-S) Cell Technology to 450WH/kg
[23]   Synthesis and electrochemical performance of polyaniline @MnO2/graphene ternary composites for electrochemical supercapacitors [J].
Pan, Chao ;
Gu, Haiteng ;
Dong, Li .
JOURNAL OF POWER SOURCES, 2016, 303 :175-181
[24]   Advanced materials for aqueous supercapacitors in the asymmetric design [J].
Rajkumar, Muniyandi ;
Hsu, Chun-Tsung ;
Wu, Tzu-Ho ;
Chen, Ming-Guan ;
Hu, Chi-Chang .
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2015, 25 (06) :527-544
[25]   X-RAY PHOTOELECTRON AND AUGER-SPECTROSCOPY STUDY OF SOME VANADIUM-OXIDES [J].
SAWATZKY, GA ;
POST, D .
PHYSICAL REVIEW B, 1979, 20 (04) :1546-1555
[26]  
Stranick M. A., 1993, Surface Science Spectra, V2, P50, DOI 10.1116/1.1247724
[27]   Spectroscopy of thin polyaniline films deposited during chemical oxidation of aniline [J].
Trchova, Miroslava ;
Moravkova, Zuzana ;
Sedenkova, Ivana ;
Stejskal, Jaroslav .
CHEMICAL PAPERS, 2012, 66 (05) :415-445
[28]  
Viswanathan A, 2025, Next Sustainability, V5, P100088, DOI 10.1016/j.nxsust.2024.100088
[29]   Nanoporous PANI/ZnO/VO2 ternary nanocomposite and its electrolyte for green supercapacitance [J].
Viswanathan, Aranganathan ;
Shetty, Adka Nityananda .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2024, 303
[30]   Influence of different dopants and redox forms of PANI in its crystal structure, morphology, electrochemical energy storage to variable extent, unique properties and kinetics [J].
Viswanathan, Aranganathan ;
Shetty, Adka Nityananda .
BULLETIN OF MATERIALS SCIENCE, 2022, 45 (02)