Insights into distorted lamellar phases with small-angle scattering and machine learning

被引:3
作者
Tung, Chi-Huan [1 ]
Ding, Lijie [1 ]
Huang, Guan-Rong [2 ,3 ]
Porcar, Lionel [4 ]
Shinohara, Yuya [5 ]
Sumpter, Bobby G. [6 ]
Do, Changwoo [1 ]
Chen, Wei-Ren [1 ]
机构
[1] Oak Ridge Natl Lab, Neutron Scattering Div, Oak Ridge, TN 37831 USA
[2] Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 300044, Taiwan
[3] Natl Ctr Theoret Sci, Div Phys, Taipei 10617, Taiwan
[4] Inst Laue Langevin, BP 156, F-38042 Grenoble 9, France
[5] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
[6] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
关键词
small-angle scattering; machine learning; distorted lamellar phases; regression analysis; Kolmogorov-Arnold networks; LYOTROPIC LIQUID-CRYSTAL; X-RAY-SCATTERING; SODIUM DODECYL-SULFATE; WATER-SYSTEM; ELECTRON-MICROSCOPY; AMMONIUM PERFLUORONONANOATE; NEUTRON-SCATTERING; MELTING REGIME; NMR; DEFECTS;
D O I
10.1107/S1600576725000317
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lamellar phases are essential in various soft matter systems, with topological defects significantly influencing their mechanical properties. In this report, we present a machine-learning approach for quantitatively analyzing the structure and dynamics of distorted lamellar phases using scattering techniques. By leveraging the mathematical framework of Kolmogorov-Arnold networks, we demonstrate that the conformations of these distorted phases - expressed as superpositions of complex waves - can be reconstructed from small-angle scattering intensities. Through the contour analysis of wave field phase singularities, we obtain the statistics of the spatial distribution of topological defects. Furthermore, we establish that the temporal evolution of these defects can be derived from the time-dependent traveling wave field, informed by the dispersion relation of spectral components. This method opens new avenues for investigating the dynamics of distorted lamellar phases using various dynamic scattering techniques such as neutron spin echo and X-ray photon correlation spectroscopy. These findings enhance our microscopic understanding of how defects influence the physical properties of lamellar materials, with implications for both equilibrium and non-equilibrium states in general lamellar systems.
引用
收藏
页码:523 / 534
页数:12
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