Photoluminescence;
phosphors;
solid-state reaction method;
white LEDs;
ENERGY-TRANSFER;
LUMINESCENCE PROPERTIES;
CRYSTAL-STRUCTURE;
HIGH-BRIGHTNESS;
RED PHOSPHORS;
BI3+;
UV;
IONS;
EMISSION;
EVOLUTION;
D O I:
10.1080/00084433.2025.2488593
中图分类号:
TF [冶金工业];
学科分类号:
0806 ;
摘要:
Pristine LiY(WO4)(2) and Bi3+, Eu3+ singly and co-doped LiY(WO4)(2) tungstate phosphors were synthesised using the solid-state reaction (SSR) method. Powder X-ray diffraction (PXRD) analysis confirmed the formation of a wolframite-related structure with a P2/n space group. Under ultraviolet (UV) excitation, the phosphors exhibited distinct emission colours due to efficient energy transfer (ET) from the [WO4]2- group to the Bi3+ and Eu3+ ions. The photoluminescence (PL) spectra showed greenish-yellow emission from Bi3+ at 513 nm under 336 nm excitation and red emission from Eu3+ at 615 nm under 300 nm excitation. The CIE colour coordinates, derived from the PL emission data, indicated that LiY(WO4)(2):Bi3+, Eu3+ is an efficient phosphor suitable for applications such as white light-emitting diodes (wLEDs) and display devices. On a synth & eacute;tis & eacute; des phosphores de tungstate vierges LiY(WO4)2 et LiY(WO4)2 dop & eacute;s individuellement et co-dop & eacute;s de Bi3+, Eu3+ par la m & eacute;thode de r & eacute;action & agrave; l'& eacute;tat solide (SSR). L'analyse par diffraction des rayons X de la poudre (PXRD) a confirm & eacute; la formation d'une structure apparent & eacute;e & agrave; la wolframite avec un groupe spatial P2/n. Sous excitation ultraviolette (UV), les phosphores exhibaient des couleurs d'& eacute;mission distinctes en raison d'un transfert d'& eacute;nergie (ET) efficace du groupe [WO4]2- aux ions Bi3+ et Eu3+. Les spectres de photoluminescence (PL) ont montr & eacute; une & eacute;mission jaune verd & acirc;tre du Bi3+ & agrave; 513 nm sous excitation & agrave; 336 nm et une & eacute;mission rouge du Eu3+ & agrave; 615 nm sous excitation & agrave; 300 nm. Les coordonn & eacute;es de couleur CIE, d & eacute;riv & eacute;es des donn & eacute;es d'& eacute;mission de PL, ont indiqu & eacute; que LiY(WO4)2:Bi3+, Eu3+ & eacute;tait un phosphore efficace adapt & eacute; aux applications telles que les diodes & eacute;lectroluminescentes blanches (wLED) et les dispositifs d'affichage.
机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Yang, Zhao-Ning
Li, Jun
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Li, Jun
Qiu, Jian-Bei
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Qiu, Jian-Bei
Yang, Zheng-Wen
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Yang, Zheng-Wen
Song, Zhi-Guo
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Song, Zhi-Guo
Wang, Rong-Fei
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h-index: 0
机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Wang, Rong-Fei
Yu, Xue
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Yu, Xue
Yang, Yong
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Yang, Yong
Zhou, Da-Cheng
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机构:
College of Materials Science and Engineering, Kunming University of Science and TechnologyCollege of Materials Science and Engineering, Kunming University of Science and Technology
Zhou, Da-Cheng
Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis,
2013,
33
(01):
: 19
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22
机构:
Sao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Sao Paulo State Univ, Inst Biosci Humanities & Exact Sci, UNESP, BR-15054000 Sao Jose Do Rio Preto, SP, BrazilSao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Leite Silva, C. M. B.
Bispo-Jr, A. G.
论文数: 0引用数: 0
h-index: 0
机构:
Sao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Sao Paulo State Univ, Inst Biosci Humanities & Exact Sci, UNESP, BR-15054000 Sao Jose Do Rio Preto, SP, BrazilSao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Bispo-Jr, A. G.
Lima, S. A. M.
论文数: 0引用数: 0
h-index: 0
机构:
Sao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Sao Paulo State Univ, Inst Biosci Humanities & Exact Sci, UNESP, BR-15054000 Sao Jose Do Rio Preto, SP, BrazilSao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Lima, S. A. M.
Pires, A. M.
论文数: 0引用数: 0
h-index: 0
机构:
Sao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
Sao Paulo State Univ, Inst Biosci Humanities & Exact Sci, UNESP, BR-15054000 Sao Jose Do Rio Preto, SP, BrazilSao Paulo State Univ, Sch Technol & Sci, UNESP, R Roberto Simonsen 305, BR-19060900 Presidente Prudente, SP, Brazil
机构:
Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R ChinaGuangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
Zhang, Xinguo
Chen, Mengyang
论文数: 0引用数: 0
h-index: 0
机构:
Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R ChinaGuangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
Chen, Mengyang
Zhang, Jilin
论文数: 0引用数: 0
h-index: 0
机构:
Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R ChinaGuangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
Zhang, Jilin
Qin, Xinzhen
论文数: 0引用数: 0
h-index: 0
机构:
Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R ChinaGuangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
Qin, Xinzhen
Gong, Menglian
论文数: 0引用数: 0
h-index: 0
机构:
Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R ChinaGuangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China