Photoluminescence properties of LiY(WO4)2:Bi3+, Eu3+ phosphors for white light-emitting diode applications

被引:0
|
作者
Mungale, Ankit [1 ]
Shah, Shaukat A. [1 ]
Pusdekar, Ashvini R. [2 ]
Warbhe, Rutuja [3 ]
Ugemuge, Nilesh S. [2 ]
Harnath, D. [4 ]
Moharil, Sanjiv V. [5 ]
机构
[1] Anand Niketan Coll, Dept Chem, IHLR & SS, Warora 442907, India
[2] Anand Niketan Coll, Dept Phys, HLR & SS, Warora 442907, India
[3] D DY Patil Inst Technol Pimpri, Pune, India
[4] Natl Inst Technol Warangal, Dept Phys, Hanamkonda, India
[5] RTM Nagpur Univ, Dept Phys, Nagpur, India
关键词
Photoluminescence; phosphors; solid-state reaction method; white LEDs; ENERGY-TRANSFER; LUMINESCENCE PROPERTIES; CRYSTAL-STRUCTURE; HIGH-BRIGHTNESS; RED PHOSPHORS; BI3+; UV; IONS; EMISSION; EVOLUTION;
D O I
10.1080/00084433.2025.2488593
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Pristine LiY(WO4)(2) and Bi3+, Eu3+ singly and co-doped LiY(WO4)(2) tungstate phosphors were synthesised using the solid-state reaction (SSR) method. Powder X-ray diffraction (PXRD) analysis confirmed the formation of a wolframite-related structure with a P2/n space group. Under ultraviolet (UV) excitation, the phosphors exhibited distinct emission colours due to efficient energy transfer (ET) from the [WO4]2- group to the Bi3+ and Eu3+ ions. The photoluminescence (PL) spectra showed greenish-yellow emission from Bi3+ at 513 nm under 336 nm excitation and red emission from Eu3+ at 615 nm under 300 nm excitation. The CIE colour coordinates, derived from the PL emission data, indicated that LiY(WO4)(2):Bi3+, Eu3+ is an efficient phosphor suitable for applications such as white light-emitting diodes (wLEDs) and display devices. On a synth & eacute;tis & eacute; des phosphores de tungstate vierges LiY(WO4)2 et LiY(WO4)2 dop & eacute;s individuellement et co-dop & eacute;s de Bi3+, Eu3+ par la m & eacute;thode de r & eacute;action & agrave; l'& eacute;tat solide (SSR). L'analyse par diffraction des rayons X de la poudre (PXRD) a confirm & eacute; la formation d'une structure apparent & eacute;e & agrave; la wolframite avec un groupe spatial P2/n. Sous excitation ultraviolette (UV), les phosphores exhibaient des couleurs d'& eacute;mission distinctes en raison d'un transfert d'& eacute;nergie (ET) efficace du groupe [WO4]2- aux ions Bi3+ et Eu3+. Les spectres de photoluminescence (PL) ont montr & eacute; une & eacute;mission jaune verd & acirc;tre du Bi3+ & agrave; 513 nm sous excitation & agrave; 336 nm et une & eacute;mission rouge du Eu3+ & agrave; 615 nm sous excitation & agrave; 300 nm. Les coordonn & eacute;es de couleur CIE, d & eacute;riv & eacute;es des donn & eacute;es d'& eacute;mission de PL, ont indiqu & eacute; que LiY(WO4)2:Bi3+, Eu3+ & eacute;tait un phosphore efficace adapt & eacute; aux applications telles que les diodes & eacute;lectroluminescentes blanches (wLED) et les dispositifs d'affichage.
引用
收藏
页数:12
相关论文
共 50 条
  • [41] Synthesis and photoluminescence properties of red-emitting Y6WO12:Eu3+ phosphors
    Chien, Tzu-Chin
    Yang, Ji-Chun
    Hwang, Chii-Shyang
    Yoshimura, Masahiro
    JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 676 : 286 - 291
  • [42] Photoluminescence properties of KBaY(BO3)2:Eu3+/Bi3+ phosphors excited by ultraviolet and blue light
    Xia, Siyu
    Guan, Anxiang
    Gao, Fangfang
    Fu, Anjie
    Xu, Yonghui
    Meng, Yingbin
    Zhou, Liya
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (16) : 11856 - 11860
  • [43] Effects of the homogeneous Bi3+ doping process on photoluminescence properties of YVO4:Bi3+,Eu3+ nanophosphor
    Takeshita, Satoru
    Isobe, Tetsuhiko
    Sawayama, Tomohiro
    Niikura, Seiji
    JOURNAL OF LUMINESCENCE, 2009, 129 (09) : 1067 - 1072
  • [44] Synthesis, structure and luminescence properties of TiO2:Eu3+ for white light-emitting diode
    Chen, Wanping
    Zhou, Ahong
    Yang, Xin
    Liu, Yan
    JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 581 : 330 - 334
  • [45] Synthesis and photoluminescence properties of Eu3+, Bi3+ codoped BaZrO3 phosphors
    Yang, Zhao-Ning
    Li, Jun
    Qiu, Jian-Bei
    Yang, Zheng-Wen
    Song, Zhi-Guo
    Wang, Rong-Fei
    Yu, Xue
    Yang, Yong
    Zhou, Da-Cheng
    Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2013, 33 (01): : 19 - 22
  • [46] Synthesis and Photoluminescence Properties of Eu3+, Bi3+ Codoped BaZrO3 Phosphors
    Yang Zhao-ning
    Li Jun
    Qiu Jian-bei
    Yang Zheng-wen
    Song Zhi-guo
    Wang Rong-fei
    Yu Xue
    Yang Yong
    Zhou Da-cheng
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33 (01) : 19 - 22
  • [47] Eu3+ complex/polymer films for light-emitting diode applications
    Leite Silva, C. M. B.
    Bispo-Jr, A. G.
    Lima, S. A. M.
    Pires, A. M.
    OPTICAL MATERIALS, 2019, 96
  • [48] Judd Ofelt theoretical analysis, Photoluminescence properties of Eu3+ activated LiGd(WO4)2 phosphors
    Shruthi, D. L.
    Reddy, A. Jagannatha
    Kumar, G. N. Anil
    Jayasankar, C. K.
    JOURNAL OF LUMINESCENCE, 2020, 222
  • [49] Photoluminescence studies of high-efficient red-emitting K2Y(WO4)(PO4):Eu3+ phosphor for NUV LED
    Zhang, Xinguo
    Chen, Mengyang
    Zhang, Jilin
    Qin, Xinzhen
    Gong, Menglian
    MATERIALS RESEARCH BULLETIN, 2016, 73 : 219 - 225
  • [50] SM3+-Activated LiZnPO4 Phosphors: Synthesis, Characterization, and Their Luminescent Properties for White Light-Emitting Diode Applications
    Rafiq, Haqnawaz
    Farooq, Mudasir
    Rubab, Seemin
    Rasool, Mir Hashim
    JOURNAL OF ELECTRONIC MATERIALS, 2024, 53 (06) : 2929 - 2945