Photoluminescence properties of LiY(WO4)2:Bi3+, Eu3+ phosphors for white light-emitting diode applications

被引:0
|
作者
Mungale, Ankit [1 ]
Shah, Shaukat A. [1 ]
Pusdekar, Ashvini R. [2 ]
Warbhe, Rutuja [3 ]
Ugemuge, Nilesh S. [2 ]
Harnath, D. [4 ]
Moharil, Sanjiv V. [5 ]
机构
[1] Anand Niketan Coll, Dept Chem, IHLR & SS, Warora 442907, India
[2] Anand Niketan Coll, Dept Phys, HLR & SS, Warora 442907, India
[3] D DY Patil Inst Technol Pimpri, Pune, India
[4] Natl Inst Technol Warangal, Dept Phys, Hanamkonda, India
[5] RTM Nagpur Univ, Dept Phys, Nagpur, India
关键词
Photoluminescence; phosphors; solid-state reaction method; white LEDs; ENERGY-TRANSFER; LUMINESCENCE PROPERTIES; CRYSTAL-STRUCTURE; HIGH-BRIGHTNESS; RED PHOSPHORS; BI3+; UV; IONS; EMISSION; EVOLUTION;
D O I
10.1080/00084433.2025.2488593
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Pristine LiY(WO4)(2) and Bi3+, Eu3+ singly and co-doped LiY(WO4)(2) tungstate phosphors were synthesised using the solid-state reaction (SSR) method. Powder X-ray diffraction (PXRD) analysis confirmed the formation of a wolframite-related structure with a P2/n space group. Under ultraviolet (UV) excitation, the phosphors exhibited distinct emission colours due to efficient energy transfer (ET) from the [WO4]2- group to the Bi3+ and Eu3+ ions. The photoluminescence (PL) spectra showed greenish-yellow emission from Bi3+ at 513 nm under 336 nm excitation and red emission from Eu3+ at 615 nm under 300 nm excitation. The CIE colour coordinates, derived from the PL emission data, indicated that LiY(WO4)(2):Bi3+, Eu3+ is an efficient phosphor suitable for applications such as white light-emitting diodes (wLEDs) and display devices. On a synth & eacute;tis & eacute; des phosphores de tungstate vierges LiY(WO4)2 et LiY(WO4)2 dop & eacute;s individuellement et co-dop & eacute;s de Bi3+, Eu3+ par la m & eacute;thode de r & eacute;action & agrave; l'& eacute;tat solide (SSR). L'analyse par diffraction des rayons X de la poudre (PXRD) a confirm & eacute; la formation d'une structure apparent & eacute;e & agrave; la wolframite avec un groupe spatial P2/n. Sous excitation ultraviolette (UV), les phosphores exhibaient des couleurs d'& eacute;mission distinctes en raison d'un transfert d'& eacute;nergie (ET) efficace du groupe [WO4]2- aux ions Bi3+ et Eu3+. Les spectres de photoluminescence (PL) ont montr & eacute; une & eacute;mission jaune verd & acirc;tre du Bi3+ & agrave; 513 nm sous excitation & agrave; 336 nm et une & eacute;mission rouge du Eu3+ & agrave; 615 nm sous excitation & agrave; 300 nm. Les coordonn & eacute;es de couleur CIE, d & eacute;riv & eacute;es des donn & eacute;es d'& eacute;mission de PL, ont indiqu & eacute; que LiY(WO4)2:Bi3+, Eu3+ & eacute;tait un phosphore efficace adapt & eacute; aux applications telles que les diodes & eacute;lectroluminescentes blanches (wLED) et les dispositifs d'affichage.
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页数:12
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