Cross-Electrophile Coupling of Aryl Chlorides with Alkyl Chlorides Using Rotating Magnetic Field and Metal Rods

被引：0

作者：

Feng, Xiaomei ^{[1
]}

Li, Xiangye ^{[1
]}

Zhang, Ning ^{[1
]}

Zhang, Lizhi ^{[1
]}

Sun, Fenggang ^{[1
]}

Liu, Hui ^{[1
]}

Zhao, Zengdian ^{[1
]}

Li, Xinjin ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255000, Shandong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2025年 / 147卷 / 15期

基金：

中国国家自然科学基金;

关键词：

HALIDES; CATALYSIS; BROMIDES; VINYL;

D O I：

10.1021/jacs.5c00381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pursuit of sustainable and environmentally benign methods and techniques continues to challenge organic chemists. Herein, we report the development of a novel approach in which electromagnetic induction could participate in the coupling of organic chlorides using a rotating magnetic field and metal rods. In particular, we describe the application of this strategy to the nickel-catalyzed cross-electrophile coupling of aryl chlorides with alkyl chlorides. Using these abundant and commercially available organochlorides, such a system allows reactions to proceed with a broader scope than the current protocols under mild conditions.

引用

页码：12664 / 12671

页数：8

共 49 条

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