Induction Effect of Fluorine-Grafted Polymer-Based Electrolytes for High-Performance Lithium Metal Batteries

被引：0

作者：

Haiman Hu ^{[1
]}

Jiajia Li ^{[1
]}

Fei Lin ^{[1
]}

Jiaqi Huang ^{[1
]}

Huaiyang Zheng ^{[1
]}

Haitao Zhang ^{[2
]}

Xiaoyan Ji ^{[1
]}

机构：

[1] Luleå University of Technology,Energy Engineering, Division of Energy Science

[2] Chinese Academy of Sciences,CAS Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering

来源：

Nano-Micro Letters | 2025年 / 17卷 / 1期

关键词：

Fluorine-grafted polymer; Induction effect; High interface stability; Quasi-solid-state electrolytes; Lithium metal battery;

D O I：

10.1007/s40820-025-01738-9

中图分类号：

学科分类号：

摘要：

Fluorine-grafted quasi-solid-state composite electrolyte (F-QSCE)@30 exhibits high ionic conductivity of 1.21 mS cm–1 at 25 °C.The inductive effect weakens the coordination between Li+ and TFSI‒, enhancing Li+ transport.LiF in the solid electrolyte interphase of F-QSCE@30 comes from decomposed F segments, not TFSI‒.F-QSCE@30 maintains stability with Li metal for over 4000 h and inhibits dendrite growth.

引用

共 50 条

[1] Dielectric polymer based electrolytes for high-performance all-solid-state lithium metal batteries
Kang, Qi
Li, Yong
Zhuang, Zechao
Wang, Dingsheng
Zhi, Chunyi
Jiang, Pingkai
Huang, Xingyi
JOURNAL OF ENERGY CHEMISTRY, 2022, 69 : 194 - 204
[2] Stepwise optimization of single-ion conducting polymer electrolytes for high-performance lithium-metal batteries
Dong, Xu
Chen, Zhen
Gao, Xinpei
Mayer, Alexander
Liang, Hai-Peng
Passerini, Stefano
Bresser, Dominic
JOURNAL OF ENERGY CHEMISTRY, 2023, 80 : 174 - 181
[3] Designing Bilayer Heterostructure Functional Polymer Electrolytes with Interfacial Engineering Strategy for High-Performance Lithium Metal Batteries
Ma, Longli
Tan, Jian
Ren, Zhouhong
Feng, Bingjian
Liu, Zhu
Yi, Pengshu
Cao, Shaochong
Lu, Wenyi
Liu, Yongshuai
Ye, Chuming
Ye, Mingxin
Fang, Huayi
Shen, Jianfeng
ADVANCED FUNCTIONAL MATERIALS, 2025, 35 (06)
[4] Lithium sulfonate-based polyether gel polymer electrolytes with high ionic conductivity and uniform Li-ion transport for high-performance lithium metal batteries
Hu, Zhenyuan
Liu, Ziying
Liu, Kai
Qin, Jinpeng
Guo, Wenfan
Fan, Weizhen
Zhang, Yunfeng
SCIENCE CHINA-MATERIALS, 2025, 68 (02) : 493 - 502
[5] Combining ternary, ionic liquid-based, polymer electrolytes with a single-ion conducting polymer-based interlayer for lithium metal batteries
Wan, Jiajia
Wan, Mintao
Hou, Xu
Vangosa, Francesco Briatico
Bresser, Dominic
Li, Jie
Paillard, Elie
ENERGY MATERIALS, 2024, 4 (06):
[6] Effect of interface wetting on the performance of gel polymer electrolytes-based solid-state lithium metal batteries
Pan, Xiaona
Liu, Lei
Yang, Peixia
Zhang, Jinqiu
An, Maozhong
SOLID STATE IONICS, 2020, 357 (357)
[7] Multifunctional polymer bottlebrush-based gel polymer electrolytes for lithium metal batteries
Jia, D.
Cui, Y.
Liu, Q.
Zhou, M.
Huang, J.
Liu, R.
Liu, S.
Zheng, B.
Zhu, Y.
Wu, D.
MATERIALS TODAY NANO, 2021, 15
[8] Crosslinked Hyperbranched Polyglycerol-Based Polymer Electrolytes for Lithium Metal Batteries
Neumann, Niklas
Abels, Gideon
Koschek, Katharina
Boskamp, Laura
BATTERIES-BASEL, 2023, 9 (09):
[9] Multifunctional quasi-solid state electrolytes based on "reverse" plant cell structure for high-performance lithium metal batteries
Liu, Zixin
Wu, Feng
Zhang, Xixue
Sun, Xuan
Yang, Binbin
Sun, Wen
Chen, Renjie
Li, Li
ENERGY STORAGE MATERIALS, 2024, 72
[10] Effect of Organic Functional Groups on Poly(ethylene oxide) Electrolytes for High-Performance Solid-State Lithium-Metal Batteries
Zhang, Zhao
Cai, Lucheng
Huang, Pengfei
Zhang, Zhihao
Ying, Hangjun
Han, Gaorong
Han, Wei-Qiang
ACS APPLIED ENGINEERING MATERIALS, 2023, 1 (08): : 2163 - 2173

← 1 2 3 4 5 →