Ultrasensitive electrochemical sensor for vanillin based on CuS doped highly conductive carbon materials

被引:2
作者
Wang, Hui [1 ]
Li, Jiejun [1 ]
Zhao, Pengcheng [1 ]
Fei, Junjie [1 ,3 ]
Xie, Yixi [1 ,2 ]
机构
[1] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China
[2] Xiangtan Univ, Hunan Prov Univ Key Lab Environm & Ecol Hlth, Xiangtan 411105, Peoples R China
[3] Xiangtan Univ, Hunan Inst Adv Sensing & Informat Technol, Xiangtan 411105, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrochemical detection; Food analysis; Highly conductive carbon materials; Vanillin; ELECTRODE; BLACK;
D O I
10.1016/j.foodchem.2025.144093
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Herein, a sensitive and selective electrochemical sensor modified with CuS doped highly conductive carbon materials (HCC) were successfully used to detect vanillin (VAN), which manufactured in a low temperature one step process. Experimental analysis by differential pulse voltammetry (DPV) and cyclic voltammetry (CV) under optimised conditions revealed excellent rate characteristics due to sub-micron spherical particles on the surface of CuS nanoparticles and synergistic effects with the excellent electrical conductivity of HCC. The prepared functionalized CuS-HCC/GCE has an ultra high specific surface area (10.85 mm2) and selective VAN determination, whose detection limit and linear range of VAN sensor are 61 pM and 0.1 nM-120 mu M respectively, and has a terrific recovery rate in food samples (96.7 % to 103.8 %). These results show that this work has provided a new promising food sensor for detecting VAN.
引用
收藏
页数:12
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