Synergistic effects of magnetic fields and flow velocity on hydrogen bubble dynamics in water electrolysis

被引:0
作者
Sun, Jindong [1 ]
Wang, Caizhu [1 ]
Wen, Haoyu [1 ]
Yin, Qian [1 ]
Fan, Jiaci [1 ]
机构
[1] Beijing Univ Civil Engn & Architecture, Sch Environm & Energy Engn, Beijing 100044, Peoples R China
关键词
Magnetic field; Flow velocity; Electrochemical reaction; Hydrogen bubble dynamics; Hydrogen evolution reaction (HER); EXCHANGE MEMBRANE ELECTROLYZER; 2-PHASE FLOW; GAS-BUBBLES; CONVECTION; DETACHMENT; LORENTZ; SURFACE; GROWTH; MICROELECTRODE; PERFORMANCE;
D O I
10.1016/j.elecom.2025.107918
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
By systematically regulating the magnetic field intensity and electrolyte flow rate, this study investigates the coupling effects of magnetic fields and flow velocity on hydrogen bubble dynamics during water electrolysis. A model of hydrogen bubble dynamics was used to analyze nucleation, growth, and detachment mechanisms under magnetic-flow coupling, determining key parameters such as growth radius and detachment speed. The dynamic evolution of hydrogen bubbles was comprehensively analyzed under both static and dynamic flow conditions. Electrochemical measurements revealed that increasing the magnetic field intensity from 0 T to 0.3 T enhanced the current density by 9.61 % at 0 cm/s and 6.67 % at 1 cm/s flow rates. These results suggest that magnetic-flow coupling reduces concentration polarization and overpotential. However, the enhancement effect gradually diminished with increasing flow velocity. Visualization experiments further confirmed that the coupling between magnetic field and flow velocity significantly promoted bubble oscillation, coalescence, and detachment, thereby improving electrolysis performance.
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页数:15
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共 83 条
  • [1] Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors
    Angulo, Andrea
    van der Linde, Peter
    Gardeniers, Han
    Modestino, Miguel
    Rivas, David Fernandez
    [J]. JOULE, 2020, 4 (03) : 555 - 579
  • [2] [Anonymous], 2006, Fuel Cells: From Fundamentals to Applications, DOI DOI 10.1007/0-387-35402-62
  • [3] Two-dimensional model of low-pressure PEM electrolyser: Two-phase flow regime, electrochemical modelling and experimental validation
    Aubras, F.
    Deseure, J.
    Kadjo, J. J. A.
    Dedigama, I.
    Majasan, J.
    Grondin-Perez, B.
    Chabriat, J. -P.
    Brett, D. J. L.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (42) : 26203 - 26216
  • [4] On the Electrolyte Convection around a Hydrogen Bubble Evolving at a Microelectrode under the Influence of a Magnetic Field
    Baczyzmalski, Dominik
    Karnbach, Franziska
    Yang, Xuegeng
    Mutschke, Gerd
    Uhlemann, Margitta
    Eckert, Kerstin
    Cierpka, Christian
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (09) : E248 - E257
  • [5] On the growth regimes of hydrogen bubbles at microelectrodes
    Bashkatov, Aleksandr
    Hossain, Syed Sahil
    Mutschke, Gerd
    Yang, Xuegeng
    Rox, Hannes
    Weidinger, Inez M.
    Eckert, Kerstin
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (43) : 26738 - 26752
  • [6] The effect of magnetic and optic field in water electrolysis
    Bidin, Noriah
    Azni, Siti Radhiana
    Islam, Shumaila
    Abdullah, Mundzir
    Ahmad, M. Fakaruddin Sidi
    Krishnan, Ganesan
    Johari, A. Rahman
    Bakar, M. Aizat A.
    Sahidan, Nur Syahirah
    Musa, NurFatin
    Salebi, M. Farizuddin
    Razali, Nagiuddin
    Sanagi, Mohd Marsin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (26) : 16325 - 16332
  • [7] GROWTH-KINETICS OF BUBBLES ELECTROGENERATED AT MICROELECTRODES
    BRANDON, NP
    KELSALL, GH
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1985, 15 (04) : 475 - 484
  • [8] A comprehensive review on PEM water electrolysis
    Carmo, Marcelo
    Fritz, David L.
    Merge, Juergen
    Stolten, Detlef
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (12) : 4901 - 4934
  • [9] Alternative Energy Carriers: Unique Interfaces for Electrochemical Hydrogenic Transformations
    Carroll, Gerard M.
    Gebbie, Matthew A.
    Stahl, Shannon S.
    Johnson, Mathew R.
    Luca, Oana R.
    Petersen, Haley A.
    Bomble, Yannick J.
    Neale, Nathan R.
    Cortright, Randy D.
    [J]. ADVANCED ENERGY MATERIALS, 2023, 13 (14)
  • [10] Bubble generation in quiescent and co-flowing liquids
    Chakraborty, I.
    Biswas, G.
    Ghoshdastidar, P. S.
    [J]. INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2011, 54 (21-22) : 4673 - 4688