Hydrogen Yield from the Partial Oxidation of Methane: Effect of Sc Promoter on Supported Ni/MCM-41 Catalyst

This study explores the impact of scandium (Sc) as a promoter on the catalytic performance of 4Ni/MCM-41 catalysts for the partial oxidation of methane (POM). 4Ni+Sc/MCM-41 catalysts were synthesized with varying Sc loadings of 0, 0.2, 0.4, 0.6, and 0.8 wt.%. These catalysts were characterized using several techniques, including N2 physisorption, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), Raman spectroscopy, thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). All catalysts exhibited a mesoporous structure characterized by narrow slit-shaped pores. Among them, the 4Ni+0.2Sc/MCM-41 catalyst showed the most consistent pore size distribution. The addition of Sc (scandium) facilitated the formation of strongly interacting nickel species, which enhanced the initial catalytic activity. However, a trade-off was observed between initial activity and long-term stability. The optimal Sc loading was determined to be 0.2 wt.%. This catalyst achieved the highest methane conversion rate of 63.9%, a hydrogen yield of 60%, and an H2/CO ratio of 2.7 while also demonstrating superior stability during extended operation. The 4Ni+0.2Sc/MCM-41 catalyst showed only a 7% weight loss in the thermogravimetric analysis (TGA), which shows that it will stay stable even after being used for a long time. The improved performance of the Sc-promoted catalysts is attributable to the increased availability of active sites, enhanced stability, and better dispersion of nickel. These efforts aim to create more sustainable and efficient methods for hydrogen production, minimizing the negative effects associated with traditional processes. By advancing these technologies, we can further support the transition to a cleaner energy future.