Efficient Conversion of Glucose into Lactic Acid over the Lewis Acidity Enhanced Sn-Beta Catalyst

被引:0
作者
Guo, Fenfen [1 ]
Wang, Yuxuan [1 ]
Jiang, Zhicheng [1 ]
Tu, Youjing [1 ]
Li, Ruikai [1 ]
Zhang, Xingyu [1 ]
Tang, Aoyi [1 ]
Liang, Yuan [1 ]
Yan, Lishi [2 ]
Luo, Hu [3 ]
Li, Shenggang [3 ]
Kong, Lingzhao [1 ]
机构
[1] Suzhou Univ Sci & Technol, Sch Environm Sci & Engn, Suzhou 215009, Peoples R China
[2] Suzhou Univ Sci & Technol, Sch Chem & Life Sci, Suzhou 215009, Peoples R China
[3] Chinese Acad Sci, Shanghai Adv Res Inst, CAS Key Lab Low Carbon Convers Sci & Engn, Shanghai 201210, Peoples R China
基金
中国国家自然科学基金;
关键词
Sn-Beta catalyst; glucose; lactic acid; Lewis acidity; ZEOLITE CATALYST; BIOMASS; SUGARS;
D O I
10.3390/molecules30071457
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The catalytic production of lactic acid from carbohydrates was considered a green way to efficiently utilize renewable biomass resources. In this study, an easy post-synthesis method was used to prepare a Sn-Beta catalyst for the production of lactic acid from glucose at 180 degrees C, 2 MPa, and 30 min. With optimized reaction time, temperature, pressure, and the ratio of raw material to catalyst, the yield of lactic acid reached an astonishingly high level of 76.0%. In addition, the catalyst characterizations were performed in-depth, revealing the intrinsic relationship between catalyst performance and structure, proving that the 2 wt% Sn was uniformly dispersed in the skeleton of Beta zeolite, which significantly increased the density of Lewis acid. Thus, the enhanced isomerization and retro-aldol condensation processes over the Lewis acid sites led to the high yield of lactic acid. This catalytic system kept stable after five cycles at mild conditions, showing high potential for industrial biomass utilization.
引用
收藏
页数:11
相关论文
共 44 条
[1]   The role of aluminum in Sn-Al-beta zeolite catalyzing the conversion of glucose to methyl lactate [J].
Bai, Jing ;
Ling, Wenmeng ;
Chen, Weiyu ;
Liu, Yuwen ;
Sun, Pengyao ;
Wang, Haiyong ;
Wang, Chenguang .
MOLECULAR CATALYSIS, 2023, 541
[2]   Reaction pathways and selectivity in chemo-catalytic conversion of biomass-derived carbohydrates to high-value chemicals: A review [J].
Bayu, Asep ;
Abudula, Abuliti ;
Guan, Guoqing .
FUEL PROCESSING TECHNOLOGY, 2019, 196
[3]   Catalytic conversion of lignocellulosic biomass into chemicals and fuels [J].
Deng, Weiping ;
Feng, Yunchao ;
Fu, Jie ;
Guo, Haiwei ;
Guo, Yong ;
Han, Buxing ;
Jiang, Zhicheng ;
Kong, Lingzhao ;
Li, Changzhi ;
Liu, Haichao ;
Nguyen, Phuc T. T. ;
Ren, Puning ;
Wang, Feng ;
Wang, Shuai ;
Wang, Yanqin ;
Wang, Ye ;
Wong, Sie Shing ;
Yan, Kai ;
Yan, Ning ;
Yang, Xiaofei ;
Zhang, Yuanbao ;
Zhang, Zhanrong ;
Zeng, Xianhai ;
Zhou, Hui .
GREEN ENERGY & ENVIRONMENT, 2023, 8 (01) :10-114
[4]   Production of organic acids from biomass resources [J].
Deng, Weiping ;
Wang, Ye ;
Yan, Ning .
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2016, 2 :54-58
[5]   Cooperative Catalysis for Multistep Biomass Conversion with Sn/Al Beta Zeolite [J].
Dijkmans, Jan ;
Dusselier, Michiel ;
Gabriels, Dries ;
Houthoofd, Kristof ;
Magusin, Pieter C. M. M. ;
Huang, Shuigen ;
Pontikes, Yiannis ;
Trekels, Maarten ;
Vantomme, Andre ;
Giebeler, Lars ;
Oswald, Steffen ;
Sels, Bert F. .
ACS CATALYSIS, 2015, 5 (02) :928-940
[6]   Toward rational design of hierarchical beta zeolites: An overview and beyond [J].
Fernandez, Sergio ;
Ostraat, Michele L. ;
Zhang, Ke .
AICHE JOURNAL, 2020, 66 (09)
[7]   A review of comprehensive utilization of biomass to synthesize carbon nanotubes: From chemical vapor deposition to microwave pyrolysis [J].
Ge, Lichao ;
Zuo, Mingjin ;
Wang, Yang ;
Wang, Ruikun ;
Rong, Nai ;
Qi, Zhifu ;
Zhao, Can ;
Zhang, Yuli ;
Xu, Chang .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2024, 177
[8]   Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts [J].
Holm, Martin Spangsberg ;
Saravanamurugan, Shunmugavel ;
Taarning, Esben .
SCIENCE, 2010, 328 (5978) :602-605
[9]   Selective conversion of trioses to lactates over Lewis acid heterogeneous catalysts [J].
Li, Li ;
Stroobants, Christophe ;
Lin, Kaifeng ;
Jacobs, Pierre A. ;
Sels, Bert F. ;
Pescarmona, Paolo P. .
GREEN CHEMISTRY, 2011, 13 (05) :1175-1181
[10]  
Li Y., 2024, Green, Carbon, V2, P383