Multifunctional g-C3N4/NixMg1-xFe2O4 nanocomposites: Advanced materials for electrochemical energy storage and biocompatibility

被引:2
作者
Manohar, Ala [1 ]
Suvarna, Thirukachhi [2 ]
Vattikuti, S. V. Prabhakar [3 ]
Manivasagan, Panchanathan [4 ]
Jang, Eue-Soon [4 ]
Kim, Beomjin [1 ]
Sambasivam, Sangaraju [5 ]
Tighezza, Ammar M. [6 ]
Kim, Ki Hyeon [1 ]
机构
[1] Yeungnam Univ, Dept Phys, Gyongsan 38541, South Korea
[2] Osmania Univ, Dept Phys, Hyderabad 500007, India
[3] Yeungnam Univ, Sch Mech Engn, Gyongsan 38541, South Korea
[4] Kumoh Natl Inst Technol, Dept Chem & Bio Sci, Daehak Ro 61, Gumi 39177, South Korea
[5] United Arab Emirates Univ, Natl Water & Energy Ctr, Al Ain 15551, U Arab Emirates
[6] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
基金
新加坡国家研究基金会;
关键词
Ferrites; Morphology; Chemical states; Specific capacitance; Cell viability; SUPERCAPACITOR;
D O I
10.1016/j.colsurfa.2025.136618
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The increasing demand for sustainable energy sources has spurred research into advanced energy storage technologies, with supercapacitors showing significant promise. This research investigates the viability of g-C3N4/NixMg1-xFe2O4 nanocomposites (where x = 0.4 and 0.5) designated NMFG1 and NMFG2 for both electrochemical energy storage and their biocompatibility. Crystalline structures of g-C3N4, NiFe2O4, and MgFe2O4 were confirmed using X-ray diffraction (XRD), revealing average crystallite sizes in the 7-8 nm range. The morphology and elemental distribution of the synthesized materials were examined via field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Energy-dispersive X-ray spectroscopy (EDX) and elemental mapping corroborated the uniform distribution of elements within the nanocomposites. Magnetic analysis revealed superparamagnetic behavior, with an increase in saturation magnetization (Ms) from 3.96 emu/g to 4.47 emu/g. Electrochemical studies highlighted their pseudocapacitive behavior, achieving specific capacitance (Cs) values of 88 Fg(-)(1) and 78.2 Fg(-)(1) for NMFG1 and NMFG2 electrodes, with excellent cyclic stability over 10,000 cycles. Biocompatibility assays demonstrated high cell viability (> 85 %) and insignificant cytotoxicity, confirming their suitability for biomedical applications. These findings position the synthesized nanocomposites as promising candidates for multifunctional applications, including energy storage, and biomedicine.
引用
收藏
页数:12
相关论文
共 50 条
[41]   Electrochemical charge storage performance of mesoporous MoO3@Co3O4 nanocomposites as electrode materials [J].
Mohapatra, Dillip Kumar ;
Praharaj, Swetapadma ;
Rout, Dibyaranjan .
NANOTECHNOLOGY, 2022, 33 (15)
[42]   Nanocomposites of SnO2 and g-C3N4: Preparation, characterization and photocatalysis under visible LED irradiation [J].
Praus, Petr ;
Svoboda, Ladislav ;
Dvorsky, Richard ;
Reli, Martin .
CERAMICS INTERNATIONAL, 2018, 44 (04) :3837-3846
[43]   Microwave Pyrolysis and Electrochemical Supercapacitor of S-doped g-C3N4 Nanoparticles [J].
Liu Min-Min ;
He Na-Ting ;
Guo Hong-Xu ;
Ying Shao-Ming ;
Chen Zhang-Xu .
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 40 (06) :806-810
[44]   Fabrication of CuFe2O4@g-C3N4@GNPs nanocomposites as anode material for supercapacitor applications [J].
Polat, Safa ;
Faris, Dana .
CERAMICS INTERNATIONAL, 2022, 48 (17) :24609-24618
[45]   Engineering built-in electric fields within Co3O4 /g-C3N4 heterostructures for enhanced electrochemical performance in supercapacitor [J].
Zhang, Jin-hua ;
Zhu, Peng-jie ;
Liu, Yan-zhen ;
Zhu, Xiang-ru ;
Li, Yong-feng ;
Chen, Cheng-Meng .
JOURNAL OF ENERGY STORAGE, 2025, 112
[46]   Development of Fe2O3 heterostructures anchored on 2D g-C3N4 composite electrode materials for supercapacitor activities [J].
Shembade, Umesh, V ;
Shinde, Babasaheb T. ;
Magadum, Mayuri G. ;
Wategaonkar, Sandeep B. ;
Chavan, Hemant, V ;
Hatshan, Mohammad Rafe ;
Kumar, Kulurumotlakatla Dasha ;
Moholkar, Annasaheb, V .
SOLID STATE SCIENCES, 2025, 164
[47]   Boosting the lithium storage performance of Na2Li2Ti6O14 anodes by g-C3N4 modification [J].
Li, Ying ;
Wang, Fanfan ;
Li, Xue-Zhong ;
Gui, Xuan ;
Zhu, Yan-Rong ;
Cui, Ping ;
Yi, Ting-Feng .
DALTON TRANSACTIONS, 2021, 50 (15) :5208-5217
[48]   Combining in-situ sedimentation and carbon-assisted synthesis of Co3O4/g-C3N4 nanocomposites for improved supercapacitor performance [J].
Zhang, Yanjun ;
Chang, Liu ;
Chang, Xiaokai ;
Chen, Hongmei ;
Li, Yuankai ;
Fan, Yanyun ;
Wang, Jun ;
Cui, Danfeng ;
Xue, Chenyang .
DIAMOND AND RELATED MATERIALS, 2021, 111
[49]   Electrochemical energy storage and photoelectrochemical performance of Ni1-XZnXFe2O4 nanoparticles [J].
Manohar, Ala ;
Vijayakanth, V. ;
Vattikuti, S. V. Prabhakar ;
Kim, Ki Hyeon .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2023, 157
[50]   Optical and electrochemical performance of electrospun NiO-Mn3O4 nanocomposites for energy storage applications [J].
Doroudkhani, Zahra Shoghi ;
Mazloom, Jamal ;
Ghaziani, Majedeh Mahinzad .
SCIENTIFIC REPORTS, 2025, 15 (01)