Insight into the mechanism of semi-hydrogenation of phenylacetylene over Pd embedded in thioether functionalized Schiff-base linked covalent organic frameworks

被引：0

作者：

Zhao, Yiyong ^{[1
,2
]}

Sun, Jianyu ^{[1
,2
]}

Miao, Jianxin ^{[1
,2
]}

Zhang, Xinhui ^{[1
,2
]}

Wu, Han ^{[1
,2
]}

Zhang, Qunfeng ^{[1
,2
]}

Peng, Yongwu ^{[1
]}

Ding, Chengrong ^{[1
]}

Lyu, Jinghui ^{[1
,2
]}

Li, Xiaonian ^{[1
,2
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China

[2] Zhejiang Univ Technol, Zhejiang Key Lab Surface & Interface Sci & Engn Ca, Hangzhou 310014, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2025年

基金：

中国国家自然科学基金;

关键词：

SELECTIVE HYDROGENATION; PALLADIUM CATALYSTS; COFS;

D O I：

10.1039/d4cc06758d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a novel catalyst comprising palladium supported on thioether functionalized Schiff-base conjugated covalent organic frameworks, which significantly enhances the semi-hydrogenation conversion and selectivity of phenylacetylene. Theoretical calculations substantiate that the imide and thioether groups modify the electron density around Pd, reducing the energy barriers for phenylacetylene adsorption and styrene desorption, thereby improving the conversion and selectivity of the catalyst.

引用

页数：4

共 2 条

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