4-Carboxyphenyl Substituted Porphyrazine, Its Ester and Their Zinc(II) Complexes

被引：0

作者：

Ivanova, Svetlana S. ^{[1
]}

Sal'nikov, Denis S. ^{[1
]}

Rychikhina, Ekaterina D. ^{[1
]}

Stuzhin, Pavel A. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem Technol, Res Inst Macroheterocycles, Ivanovo 153000, Russia

来源：

MACROHETEROCYCLES | 2023年 / 16卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

Porphyrazines; zinc complexes; carboxyl groups; photosensitizes; ligands for HOFs; PHTHALOCYANINES;

D O I：

10.6060/mhc235568i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The porphyrazines bearing eight 4-carboxyphenyl and 4-butoxycarbonylphenyl groups (H2Pz(PhCOOH)8 and H2Pz(PhCOOBu)8), as well as their Zn(II) complexes were obtained and characterized by spectral methods. The conversion of carboxyl derivatives into their anionic forms H2Pz(PhCOO-)8 and ZnPz(PhCOO-)8 in the presence of alkali leads to water-soluble species. ZnPz(PhCOOH)8 and ZnPz(PhCOOBu)8 possess the high ability to generate singlet oxygen in DMF solutions (& Fcy;Delta = 80-83%), while their metal free analogues are weak photosensitizers due to their aggregation tendency.

引用

页码：287 / 290

页数：67

共 21 条

[1] Synthesis and photophysical properties of covalent conjugates of aqua platinum(II) and octacarboxy-substituted zinc phthalocyanine [J].

Bulgakov, Roman A. ;

Kuznetsova, Nina A. ;

Dolotova, Olga V. ;

Solovieva, Ludmila I. ;

Mack, John ;

Chidawanyika, Wadzanai J. U. ;

Kaliya, Oleg L. ;

Nyokong, Tebello .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2012, 16 (11) :1217-1224

[2] Synthetic pathways to water-soluble phthalocyanines and close analogs [J].

Dumoulin, Fabienne ;

Durmus, Mahmut ;

Ahsen, Vefa ;

Nyokong, Tebello .

COORDINATION CHEMISTRY REVIEWS, 2010, 254 (23-24) :2792-2847

[3] Porous porphyrin-based metal-organic frameworks: synthesis, structure, sorption properties and application prospects [J].

Gorbunova, Yulia G. ;

Enakieva, Yulia Yu. ;

V. Volostnykh, Marina ;

Sinelshchikova, Anna A. ;

Abdulaeva, Inna A. ;

Birin, Kirill P. ;

Tsivadze, Aslan Yu. .

RUSSIAN CHEMICAL REVIEWS, 2022, 91 (04)

[4] Two-Dimensional Covalent Organic Frameworks with Cobalt(II)-Phthalocyanine Sites for Efficient Electrocatalytic Carbon Dioxide Reduction [J].

Han, Bin ;

Ding, Xu ;

Yu, Baoqiu ;

Wu, Hui ;

Zhou, Wei ;

Liu, Wenping ;

Wei, Chuangyu ;

Chen, Baotong ;

Qi, Dongdong ;

Wang, Hailong ;

Wang, Kang ;

Chen, Yanli ;

Chen, Banglin ;

Jiang, Jianzhuang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (18) :7104-7113

[5] Water-soluble sulfonated phosphorus(v) corrolazines and porphyrazines: the effect of macrocycle contraction and pyrazine ring fusion on spectral, acid-base and photophysical properties [J].

Ivanova, Svetlana S. ;

Salnikov, Denis S. ;

Knorr, Gleb ;

Ledovich, Olesja ;

Sliznev, Valerij ;

Kubat, Pavel ;

Novakova, Veronika ;

Stuzhin, Pavel A. .

DALTON TRANSACTIONS, 2022, 51 (04) :1364-1377

[6] Effect of pH on Acid-Base and Photophysicochemical Properties of 2,3,9,10,16,17,23,24-Octacarboxyphthalocyanines in Aqueous Media [J].

Kaliya, Oleg L. ;

Kuznetsova, Nina A. ;

Bulgakov, Roman A. ;

Solovyova, Ludmila I. ;

Shevchenko, Ekaterina N. ;

Slivka, Ludmila K. ;

Lukyanets, Evgeny A. .

MACROHETEROCYCLES, 2016, 9 (02) :186-192

[7] SYNTHESIS OF OCTACARBOXYTETRA(2,3-PYRAZINO)PORPHYRAZINE - NOVEL WATER-SOLUBLE PHOTOSENSITIZERS FOR PHOTODYNAMIC THERAPY [J].

KUDREVICH, SV ;

GALPERN, MG ;

VANLIER, JE .

SYNTHESIS-STUTTGART, 1994, (08) :779-781

[8] Zinc Carboxyphthalocyanines: Synthesis, Properties, Photocatalysis [J].

Kuznetsova, Nina A. ;

Fedorova, Tatyana M. ;

Solovyova, Ludmila, I ;

Shevchenko, Ekaterina N. ;

Bordaev, Eduard B. ;

Bulgakov, Roman A. ;

Kaliya, Oleg L. ;

Lukyanets, Evgeny A. .

MACROHETEROCYCLES, 2018, 11 (01) :21-28

[9] Influence of Central versus Peripheral Coordination of Pt and Pd Atoms on Physical-Chemical Properties of Octa-4,5-carboxyphthalocyanines [J].

Kuznetsova, Nina A. ;

Bulgakov, Roman A. ;

Solovyova, Ludmila I. ;

Shevchenko, Ekaterina N. ;

Kaliya, Oleg L. ;

Lukyanets, Evgeny A. .

MACROHETEROCYCLES, 2015, 8 (02) :143-149

[10] Synthesis and photophysicochemical studies of non-metal 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine [J].

Kuznetsova, Nina A. ;

Shevchenko, Ekaterina N. ;

Makarov, Dmitry A. ;

Slivka, Ludmila K. ;

Solovyova, Ludmila I. ;

Kaliya, Oleg L. ;

Lukyanets, Evgeny A. .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2012, 16 (12) :1244-1251

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