Synthesis, crystal structure and Hirshfeld surface analysis of [1-(4-bromophenyl)-1H-1,2,3-triazol-4-yl]methyl 2-(4-nitrophenoxy)acetate

被引：1

作者：

Hakimov, Muminjon ^{[1
]}

Khozhimatova, Shakhnoza ^{[2
]}

Ortikov, Ilkhomjon ^{[3
]}

Abdugafurov, Ibragimdjan ^{[4
]}

Tojiboev, Akmaljon ^{[1
,5
]}

机构：

[1] Namangan State Univ, Boburshoh Str 161, Namangan 160107, Uzbekistan

[2] Andijan Machine Bldg Inst, Bobur Shox Ave 56, Andijan 170119, Uzbekistan

[3] Uzbek Acad Sci, Inst Chem Plant Subst, Mirzo Ulugbek Str 77, Tashkent 100170, Uzbekistan

[4] Natl Univ Uzbekistan, Univ Str 4, Tashkent 100174, Uzbekistan

[5] Univ Geol Sci, Olimlar Str 64, Tashkent 100170, Uzbekistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷

关键词：

crystal structure; 1,2,3-triazole; click chemistry; hydrogen bonds; Hirshfeld surface analysis; QUANTITATIVE-ANALYSIS;

D O I：

10.1107/S2056989024007436

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C17H13BrN4O5, was synthesized by a Cu2Br2-catalysed Meldal-Sharpless reaction between 4-nitrophenoxyacetic acid propargyl ether and para-bromophenylazide, and characterized by X-ray structure determination and H-1 NMR spectroscopy. The molecules, with a near-perpendicular orientation of the bromophenyl-triazole and nitrophenoxyacetate fragments, are connected into a three-dimensional network by intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds (confirmed by Hirshfeld surface analysis), pi-pi and Br-pi interactions.

引用

页码：910 / +

页数：8

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