Morphological and optical investigation of Ce doped La2O3 nanoparticles for photocatalytic applications

被引:1
作者
Karthikeyan, Subramani [1 ]
Sasikumar, Ponnusamy [2 ]
Arumugam, Jayachandhiran [3 ]
Abbas, Mohamad Abd E. [4 ]
Nithiyanantham, Subramanian [5 ]
机构
[1] Periyar Univ, Ctr PG & Res Studies, Dept Phys, Dharmapuri 635205, Tamil Nadu, India
[2] SIMATS, Saveetha Sch Engn, Dept Phys, Chennai, Tamil Nadu, India
[3] Velammal Coll Engn, Dept Phys, Chennai, Tamil Nadu, India
[4] King Khalid Univ, Coll Engn, Elect Engn Dept, Abha, Saudi Arabia
[5] Thiru Vi Ka Govt Arts Coll, PG & Res Dept Phys, Thiruvarur 610003, Tamil Nadu, India
关键词
FESEM; FT-IR; photo catalysis; THIN-FILMS; HYDROPHILIC PROPERTIES; PERFORMANCE; CATALYST; BEHAVIOR;
D O I
10.1002/vjch.202400105
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The simple hydrothermal approach was used to create various morphologies of cerium (Ce) substituted lanthanum oxide (La2O3) nanostructures, with a reaction time of 6 h at 100 degrees C. The research on Ce-substituted La2O3's morphology, particle size, band gap, and photocatalytic efficacy are affected by calcination temperature. The powder X-ray diffraction pattern of Ce-added La2O3 nanoparticles reveals their hexagonal shape. Field emission scanning electron microscopy is used to study the morphology of freshly produced nanoparticles. The elements in the synthesized and calcined samples were proven to exist by energy dispersive X-ray analysis. La2O3 samples synthesized at room temperature and calcined at 300 and 600 degrees C are calculated to have band gap energies of 3.1, 3.0, and 2.9 eV, respectively through UV-visible spectroscopic analysis. The photoluminescence's analysis yields the exactness in activity of photo-catalyst. It's possible to match the broad peak around 439 and 1045 cm-1 with the O & horbar;H vibration.
引用
收藏
页码:416 / 422
页数:7
相关论文
共 41 条
[1]   Exploration of catalytic performance of nano-La2O3 as an efficient catalyst for dihydropyrimidinone/thione synthesis and gas sensing [J].
Adole, Vishnu Ashok ;
Pawar, Thansing Bhavsing ;
Koli, Prashant Bhimrao ;
Jagdale, Bapu Sonu .
JOURNAL OF NANOSTRUCTURE IN CHEMISTRY, 2019, 9 (01) :61-76
[2]   The role of synthesis method in hydrogen evolution activity of Ce doped ZnO/CNTs photocatalysts: A comparative study [J].
Ahmad, I. ;
Shukrullah, S. ;
Naz, M. Y. ;
Ahmed, E. ;
Ahmad, M. ;
Rehman, S. U. ;
Bhatti, H. N. ;
Ghaffar, A. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (59) :30320-30333
[3]   Applications of nano-catalyst in new era [J].
Chaturvedi, Shalini ;
Dave, Pragnesh N. ;
Shah, N. K. .
JOURNAL OF SAUDI CHEMICAL SOCIETY, 2012, 16 (03) :307-325
[4]   Catalytic performance of a Pt-Rh/CeO2-ZrO2-La2O3-Nd2O3 three-way compress nature gas catalyst prepared by a modified double-solvent method [J].
Chen Jianjun ;
Hu Wei ;
Huang Fujin ;
Li Guangxia ;
Yuan Shandong ;
Gong Maochu ;
Zhong Lin ;
Chen Yaoqiang .
JOURNAL OF RARE EARTHS, 2017, 35 (09) :857-866
[5]   From Khoi-San indigenous knowledge to bioengineered CeO2 nanocrystals to exceptional UV-blocking green nanocosmetics [J].
Ditlopo, N. ;
Sintwa, N. ;
Khamlich, S. ;
Manikandan, E. ;
Gnanasekaran, K. ;
Henini, M. ;
Gibaud, A. ;
Krief, A. ;
Maaza, M. .
SCIENTIFIC REPORTS, 2022, 12 (01)
[6]   Structure and morphology of synthesized lanthanum hydroxide [La(OH)3] nanocrystalline powders: study on fuel to oxidant ratio [J].
Ferby, V. Anslin ;
Raj, A. Moses Ezhil ;
Bououdina, M. .
JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, 2020, 56 (02) :711-720
[7]   Influence of Sn Doping on the Structural, Morphological, Optical and Photocatalytic Functionality of ZnO Nanostructures [J].
Ganesh Kumar, K. ;
Balaji Bhargav, P. ;
Ahmed, Nafis ;
Balaji, C. .
TRANSACTIONS ON ELECTRICAL AND ELECTRONIC MATERIALS, 2021, 22 (06) :717-724
[8]   Nanomaterials and catalysis for green chemistry [J].
Gomez-Lopez, Paulette ;
Puente-Santiago, Alain ;
Castro-Beltran, Andres ;
Nascimento, Luis Adriano Santos do ;
Balu, Alina M. ;
Luque, Rafael ;
Alvarado-Beltran, Clemente G. .
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2020, 24 :48-55
[9]  
Han M., 2020, APPL PHYS A-MATER, V126, P1
[10]   Synthesis, characterization and performance of CuO/La2O3 composite catalyst for ammonia catalytic oxidation [J].
Hung, Chang-Mao .
POWDER TECHNOLOGY, 2009, 196 (01) :56-61