Atmospheric-level carbon dioxide gas sensing using low-loss mid-IR silicon waveguides

Interest in carbon dioxide (CO2) sensors is growing rapidly due to the increasing awareness of the link between air quality and health. Indoor, high CO2 levels signal poor ventilation, and outdoor the burning of fossil fuels and its associated pollution. CO2 gas sensors based on integrated optical waveguides are a promising solution due to their excellent gas sensing selectivity, compact size, and potential for mass manufacturing large volumes at low cost. However, previous demonstrations have not shown adequate performance for atmospheric-level sensing on a scalable platform. Here, we report the clearly resolved detection of 500 ppm CO2 gas at 1 s integration time and an extrapolated 1 sigma detection limit of 73 ppm at 61 s integration time using an integrated suspended silicon waveguide at a wavelength of 4.2 mu m. Our waveguide design enables suspended strip waveguides with bottom anchors while maintaining a constant waveguide core cross-sectional geometry. This unique design results in a low propagation loss of 2.20 dB/cm. The waveguides were implemented in a 150 mm silicon on insulator (SOI) platform using standard optical lithography, providing a clear path to low-cost mass manufacturing. The low CO2 detection limit of our proposed waveguide, combined with its compatibility for high-volume production, creates substantial opportunities for waveguide sensing technology in CO2 sensing applications such as fossil fuel combustion monitoring and indoor air quality monitoring for ventilation and air conditioning systems. (c) 2025 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement