Transition metal-catalyzed cross-coupling reactions of N-aryl-2-aminopyridines

被引:1
|
作者
Doraghi, Fatemeh [1 ]
Rezainia, Lina [2 ]
Morshedsolouk, Mohammad Hossein [1 ,2 ]
Navid, Hamed [2 ]
Larijani, Bagher [1 ]
Mahdavi, Mohammad [1 ]
机构
[1] Univ Tehran Med Sci, Endocrinol & Metab Clin Sci Inst, Endocrinol & Metab Res Ctr, Tehran, Iran
[2] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran
关键词
C-H ACTIVATION; ANNULATION; FUNCTIONALIZATION; AMINATION; ALKYNES; ACCESS; ARENES;
D O I
10.1039/d4ra08384a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Due to the presence of the pyridyl directing group, N-aryl-2-aminopyridines can quickly form stable complexes with metals, leading to cyclization and functionalization reactions. A large number of N-heterocycles and nitrogen-based molecules can be easily constructed via this direct and atom-economical cross-coupling strategy. In this review, we have highlighted the transformations of N-aryl-2-aminopyridines in the presence of various transition metal catalysts, such as palladium, rhodium, iridium, ruthenium, cobalt and copper.
引用
收藏
页码:1134 / 1151
页数:18
相关论文
共 50 条
  • [1] Metal-Catalyzed Cross-Coupling Reactions of Aminopyridines
    Pires, Marina J. Dias
    Poeira, Diogo L.
    Marques, M. Manuel B.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 2015 (33) : 7197 - 7234
  • [2] Transition metal-catalyzed decarboxylative cross-coupling reactions
    Rui Shang
    Lei Liu
    Science China Chemistry, 2011, 54 : 1670 - 1687
  • [3] Transition metal-catalyzed decarboxylative cross-coupling reactions
    Shang Rui
    Liu Lei
    SCIENCE CHINA-CHEMISTRY, 2011, 54 (11) : 1670 - 1687
  • [4] Transition metal-catalyzed decarboxylative cross-coupling reactions
    SHANG Rui LIU LeiKey Laboratory of Bioorganic Phosphorus Chemistry Chemical Biology Ministry of Education
    Department of Chemistry Tsinghua University Beijing China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai China
    Science China(Chemistry), 2011, 54 (11) : 1670 - 1687
  • [5] Transition metal-catalyzed decarboxylative cross-coupling reactions
    SHANG Rui~1 & LIU Lei~1
    Department of Chemistry
    Science China(Chemistry), 2011, (11) : 1670 - 1687
  • [6] Transition metal-catalyzed cross-coupling reactions using organoindium reagents
    Zhao, Kai
    Shen, Liang
    Shen, Zhi-Liang
    Loh, Teck-Peng
    CHEMICAL SOCIETY REVIEWS, 2017, 46 (03) : 586 - 602
  • [7] Functionalization of indazoles by means of transition metal-catalyzed cross-coupling reactions
    El Kazzouli, Said
    Guillaumet, Gerald
    TETRAHEDRON, 2016, 72 (43) : 6711 - 6727
  • [8] ARYL MESYLATES IN METAL-CATALYZED HOMO-COUPLING AND CROSS-COUPLING REACTIONS .4. SCOPE AND LIMITATIONS OF ARYL MESYLATES IN NICKEL-CATALYZED CROSS-COUPLING REACTIONS
    PERCEC, V
    BAE, JY
    HILL, DH
    JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (21): : 6895 - 6903
  • [9] Reactivity and selectivity in metal-catalyzed cross-coupling reactions
    Tang, Wenjun
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [10] Metal-catalyzed cross-coupling reactions of alkyl electrophiles
    Fu, Gregory
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249