Exploring Bio-Based Monomers in Emulsion and Miniemulsion Polymerization

被引：3

作者：

Mohebbi, Sara ^{[1
]}

Hutchinson, Robin A. ^{[1
]}

Cunningham, Michael F. ^{[1
]}

机构：

[1] Queens Univ, Dept Chem Engn, Kingston, ON K7L 3N6, Canada

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2025年 / 46卷 / 12期

基金：

加拿大自然科学与工程研究理事会;

关键词：

bio-based monomers; emulsion polymerization; miniemulsion polymerization; sustainability; VERSATILE BUILDING-BLOCK; ACRYLIC-CASEIN LATEXES; SOYBEAN OIL; LAURYL METHACRYLATE; CROSS-LINKING; ITACONIC ACID; RADICAL POLYMERIZATION; SUSTAINABLE POLYMERS; METHYL-METHACRYLATE; RENEWABLE RESOURCE;

D O I：

10.1002/marc.202401097

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Sustainability is a key priority in polymer synthesis, aiming to reduce reliance on nonrenewable resources by using greener components in the polymerization process. Emulsion polymerization stands out as an environmentally friendly method for producing polymers due to its utilization of water as a dispersant. The use of renewable, bio-based materials in emulsion polymerization formulations further enhances the process sustainability. This review examines recent advancements in bio-based monomers as sustainable alternatives to petroleum-based monomers in emulsion and miniemulsion polymerization. These bio-based monomers include vegetable oils, lignin derivatives, terpenes, proteins, and carbohydrates. The most notable bio-based monomers from each category is examined, reviewing their incorporation into (mini)emulsion polymerization, the polymerization processes involved, the properties of the resulting products, and their diverse applications.

引用

页数：29

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