SENSITIVE ANALYSIS OF SOME DETRIMENTAL VOLATILE ORGANIC COMPOUNDS IN FABRIC, CARPET AND AIR FRESHENER USING SOLID PHASE EXTRACTION AND GAS CHROMATOGRAPHY-MASS SPECTROMETRY

被引:0
|
作者
Ali, Hazim M. [1 ]
Khan, Mohammad Rizwan [2 ]
Essawy, Amr A. [1 ]
Nayl, Abd El Aziz A. [1 ]
Ibrahim, Hossieny [3 ]
Gomaa, Hassanien [4 ]
Gamal, Mohammed [5 ]
Alruwaili, Yasamiyan H. [1 ]
Al Rwilly, Ghazal B. [1 ]
Hasanin, Tamer H. A. [1 ]
机构
[1] Jouf Univ, Coll Sci, Dept Chem, POB 2014, Sakaka, Aljouf, Saudi Arabia
[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
[3] Assiut Univ, Fac Sci, Dept Chem, Assiut 71515, Egypt
[4] Al Azhar Univ, Fac Sci, Dept Chem, Assiut 71524, Egypt
[5] Beni Suef Univ, Fac Pharm, Pharmaceut Analyt Chem, Alshaheed Shehata Ahmed Hegazy St, Bani Suwayf 62514, Egypt
关键词
BTEX; Styrene; Benzaldehyde; Air freshener; Solid phase extraction; Gas chromatography-mass spectrometry; LIQUID-LIQUID MICROEXTRACTION; BENZYL ALCOHOL; CARBON NANOTUBES; WATER SAMPLES; ETHYLBENZENE; BENZENE; TOLUENE; BTEX; BENZALDEHYDE; STYRENE;
D O I
10.4314/bcse.v38i6.4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Benzene, toluene, ethylbenzene and xylene are known to be lethal environmental contaminants that have carcinogenic and mutagenic influences in human being while styrene and benzaldehyde have a neurotoxic effect. In other hand, the constituents of air freshener considered as a probable source of volatile organic compound. In the present work, a solid phase extraction and gas chromatography-mass spectrometry (GC-MS) technique has been optimized and applied to the fabric, carpet and air freshener samples to determine the trace amounts of benzene, toluene, ethylbenzene, xylene, styrene and benzaldehyde. The Supelclean (TM) ENVI (TM) - 18 cartridge with dichloromethane extracting solvent were found to be the optimal procedures. The system presented excellent performance in terms of limit of detection (0.08-0.61 ng/mL), coefficient of determination (0.994-0.997), precision with the relative standard deviation values ranging from 0.05-2.57%. According to the results, the concentration of benzene, toluene, ethylbenzene, xylene, styrene and benzaldehyde in fresheners' samples was found in the range 0.03-53.27, 0.03-7.12, 0.02-6.51, 0.05-96.44, 0.04-7.06 and 0.22-23.02, respectively. The excellent recovery values were also obtained up to 99.93%. The Supelclean (TM) ENVI (TM) - 18 GC-MS system was found to appropriate for the monitoring of analytes in fabric, carpet, air freshener samples, and other samples of the similar constituents.
引用
收藏
页码:1543 / 1556
页数:14
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