A comprehensive review: Evaluating emerging green leaching technologies for recycling spent lithium-ion batteries

被引：5

作者：

Shi, Huiying ^{[1
]}

Zhang, Jianfei ^{[2
,3
]}

Ou, Leming ^{[1
]}

机构：

[1] Cent South Univ, Sch Minerals Proc & Bioengn, Changsha, Peoples R China

[2] Shandong Univ, Inst Novel Semicond, Jinan 250100, Peoples R China

[3] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

CHEMICAL ENGINEERING JOURNAL | 2025年 / 506卷

基金：

中国国家自然科学基金;

关键词：

Spent Lithium-ion Battery; Recycling; Sustainability; Leaching; Hydrometallurgy; Green Chemistry; DEEP-EUTECTIC SOLVENTS; SUPERCRITICAL CARBON-DIOXIDE; VALUE-ADDED PRODUCTS; VALUABLE METALS; ORGANIC-ACIDS; CATHODE MATERIALS; CITRIC-ACID; GRAPE SEED; RECOVERY; COBALT;

D O I：

10.1016/j.cej.2025.160006

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The market demand for lithium-ion batteries (LIBs), driven by energy storage devices such as electric vehicles, has surged, intensifying environmental concerns over spent LIB accumulation and the depletion of nonrenewable metal resources. This demand spurs technological advancements. However, traditional pyrometallurgical and acid-based hydrometallurgical methods have significant environmental drawbacks, underscoring the need for viable, green innovations in LIB recycling to ensure sustainable industry growth. Compared with pyrometallurgy, hydrometallurgy offers greater sustainability benefits. In this review, we introduce the concept of "Biomass-derived Reagents" applied to LIB recycling and systematically examine the latest feasible green leaching technologies, including deep eutectic solvent leaching, bioleaching, the development of biomassderived reagents, and the application of supercritical fluids. Each technology is critically evaluated and its future potential is discussed. This work aims to offer a practical and effective reference for sustainable technological advancements in the LIB recycling sector, contributing valuable insights for both industry development and environmental protection.

引用

页数：26

共 290 条

[1] Solubility of metal oxides in deep eutectic solvents based on choline chloride [J].

Abbott, Andrew P. ;

Capper, Glen ;

Davies, David L. ;

McKenzie, Katy J. ;

Obi, Stephen U. .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (04) :1280-1282

[2] Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Munro, HL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2001, (19) :2010-2011

[3] Innovative lithium-ion battery recycling: Sustainable process for recovery of critical materials from lithium-ion batteries [J].

Abdalla, Abdalla M. ;

Abdullah, Mas F. ;

Dawood, Mohamed K. ;

Wei, Bo ;

Subramanian, Y. ;

Azad, Atia Tasfia ;

Nourin, S. ;

Afroze, S. ;

Taweekun, Juntakan ;

Azad, Abul K. .

JOURNAL OF ENERGY STORAGE, 2023, 67

[4] Li-Ion Battery Cathode Recycling: An Emerging Response to Growing Metal Demand and Accumulating Battery Waste [J].

Akhmetov, Nikita ;

Manakhov, Anton ;

Al-Qasim, Abdulaziz S. .

ELECTRONICS, 2023, 12 (05)

[5] Recovery of lithium from spent NMC batteries through water leaching, carbothermic reduction, and evaporative crystallization process [J].

Alcaraz, Lorena ;

Rodriguez-Largo, Olga ;

Barquero-Carmona, Gorka ;

Lopez, Felix A. .

JOURNAL OF POWER SOURCES, 2024, 619

[6] Mechanistic Study of Lithium-Ion Battery Cathode Recycling Using Deep Eutectic Solvents [J].

Alhashim, Salma H. ;

Bhattacharyya, Sohini ;

Tromer, Raphael ;

Kabbani, Ahmad ;

Babu, Ganguli ;

Oliveira, Eliezer Fernando ;

Galvao, Douglas S. ;

Ajayan, Pulickel M. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (18) :6914-6922

[7] Preprocessing of spent lithium-ion batteries for recycling: Need, methods, and trends [J].

Ali, Hayder ;

Khan, Hassan Abbas ;

Pecht, Michael .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2022, 168

[8] Composition analysis of the cathode active material of spent Li-ion batteries leached in citric acid solution: A study to monitor and assist recycling processes [J].

Almeida, Jenifer Rigo ;

Moura, Mayra Nicoli ;

Barrada, Renan Vicente ;

Sartori Barbieri, Eldis Maria ;

Weitzel Dias Carneiro, Maria Tereza ;

Duarte Ferreira, Sandra Aparecida ;

Fontes Lelis, Maria de Fatima ;

Jose Geraldo de Freitas, Marcos Benedito ;

Brandao, Geisamanda Pedrini .

SCIENCE OF THE TOTAL ENVIRONMENT, 2019, 685 :589-595

[9]

[Anonymous], Lithium Ion Battery-1Ah

[10] Techno-economic feasibility analysis: The missing piece in the puzzle of deep eutectic solvents [J].

Azzouz, Amirah ;

Hayyan, Maan .

SUSTAINABLE MATERIALS AND TECHNOLOGIES, 2024, 39

← 1 2 3 4 5 6 7 8 9 10 →