Crystal structure of bis(μ2-5-nonanoylquinolin-8-olato)bis[aquadichloridoindium(III)]

被引：0
|
作者：
Fuhrmann, Betty [1 ]
Meier, Eric [1 ]
Mazik, Monika [1 ]
机构：
[1] Tech Univ Bergakad Freibe, Leipziger Str 29, D-09596 Freiberg, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2024年 / 80卷
关键词：
crystal structure; indium complex; quinoline; 8-hydroxyquinoline; hydrogen bonds; van der Waals interactions; ALUMINUM METAL-COMPLEX; SOLVENT-EXTRACTION; 8-HYDROXYQUINOLINES; GALLIUM(III); PHOTOPHYSICS;
D O I：
10.1107/S205698902400882X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Crystallization of 5-nonanoyl-8-hydroxyquinoline in the presence of InCl3 in acetonitrile yields a dinuclear In-III complex crystallizing in the space group P (1) over bar. In this complex, [In-2(C18H22NO2)(2)Cl-4(H2O)(2)], each indium ion is sixfold coordinated by two chloride ions, one water molecule and two 8-quinolinolate ions. The crystal of the title complex is composed of two-dimensional supramolecular aggregates, resulting from the linkage of the O-water-H center dot center dot center dot O=C and O-water-H center dot center dot center dot Cl hydrogen bonds as well as bifurcated C-arene-H center dot center dot center dot Cl contacts.
引用
收藏
页码：1020 / +
页数：10
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