Comparative Study on Ethanol-Based Oxygenate Synthesis via Syngas over Monometallic Rh Catalysts Supported on Different Zr-MOFs

被引:1
作者
Yu, Ruiqi [1 ]
Duan, Xiangjiang [2 ]
Yu, Xuanwang [2 ]
Zheng, Xiang [3 ]
Mao, Haifang [1 ]
Yu, Jun [1 ]
机构
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China
[2] Zhejiang Haizhou Pharmaceut Co Ltd, Taizhou 318000, Peoples R China
[3] Shanghai Inst Technol, Sch Perfume & Aroma Technol, 100 Haiquan Rd, Shanghai 201418, Peoples R China
关键词
syngas; Rh catalyst; Zr-MOFs; ethanol; C-2(+) oxygenates; METAL-ORGANIC FRAMEWORKS; CO HYDROGENATION; HIGHER ALCOHOLS; CARBON; CONVERSION; MN; NANOPARTICLES; PRECURSORS; PROMOTION; INSIGHTS;
D O I
10.3390/catal14090566
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three types of Zr-based metal-organic frameworks (Zr-MOFs) were employed as supports to prepare monometallic Rh catalysts by the impregnation method. The effects of the structural properties of Zr-MOFs on their supported monometallic Rh catalysts for syngas conversion were investigated. The results showed that, compared to catalysts with Rh@MOF-808 and Rh@UiO-66, Rh@UiO-67 had higher CO conversion and C-2(+) oxygenate selectivity. The state of the Rh site is affected by the different structure of the Zr-MOFs, which is responsible for the difference in catalytic performance. The relatively higher Rh dispersion on the UiO-67 support boosted its CO adsorption ability, and Rh@UiO-67 having the best C-2(+) oxygenate selectivity was mainly attributed to it having the highest Rh+/Rh-0 ratio.
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页数:11
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[1]   Synthesis, characterization, and catalytic activity of Rh-based lanthanum zirconate pyrochlores for higher alcohol synthesis [J].
Abdelsayed, Victor ;
Shekhawat, Dushyant ;
Poston, James A., Jr. ;
Spivey, James J. .
CATALYSIS TODAY, 2013, 207 :65-73
[2]   Active Centers of Catalysts for Higher Alcohol Synthesis from Syngas: A Review [J].
Ao, Min ;
Pham, Gia Hung ;
Sunarso, Jaka ;
Tade, Moses O. ;
Liu, Shaomin .
ACS CATALYSIS, 2018, 8 (08) :7025-7050
[3]   An analysis of the effect of zirconium precursors of MOF-808 on its thermal stability, and structural and surface properties [J].
Ardila-Suarez, Carolina ;
Rodriguez-Pereira, Jhonatan ;
Baldovino-Medrano, Victor G. ;
Ramirez-Caballero, Gustavo E. .
CRYSTENGCOMM, 2019, 21 (09) :1407-1415
[4]   Understanding Structure-Property Relationships of MoO3-Promoted Rh Catalysts for Syngas Conversion to Alcohols [J].
Asundi, Arun S. ;
Hoffman, Adam S. ;
Bothra, Pallavi ;
Boubnov, Alexey ;
Vila, Fernando D. ;
Yang, Nuoya ;
Singh, Joseph A. ;
Zeng, Li ;
Raiford, James A. ;
Abild-Pedersen, Frank ;
Bare, Simon R. ;
Bent, Stacey F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (50) :19655-19668
[5]   Rh(0) nanoparticles as catalyst precursors for the solventless hydroformylation of olefins [J].
Bruss, Arnoldo J. ;
Gelesky, Marcos A. ;
Machado, Giovanna ;
Dupont, Jairton .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 252 (1-2) :212-218
[6]   In Situ Formation of FeRh Nanoalloys for Oxygenate Synthesis [J].
Carrillo, Pamela ;
Shi, Rui ;
Teeluck, Krishani ;
Senanayake, Sanjaya D. ;
White, Michael G. .
ACS CATALYSIS, 2018, 8 (08) :7279-7286
[7]   A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].
Cavka, Jasmina Hafizovic ;
Jakobsen, Soren ;
Olsbye, Unni ;
Guillou, Nathalie ;
Lamberti, Carlo ;
Bordiga, Silvia ;
Lillerud, Karl Petter .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851
[8]   Direct conversion of syngas to ethanol over Rh/Mn-supported on modified SBA-15 molecular sieves: Effect of supports [J].
Chen, Guochang ;
Guo, Cun-Yue ;
Zhang, Xiaohui ;
Huang, Zhijun ;
Yuan, Guoqing .
FUEL PROCESSING TECHNOLOGY, 2011, 92 (03) :456-461
[9]   Cu thorn-ZrO2 interfacial sites with highly dispersed copper nanoparticles derived from Cu@UiO-67 hybrid for efficient CO2 hydrogenation to methanol [J].
Chen, Guoqing ;
Yu, Jun ;
Li, Gonghui ;
Zheng, Xiang ;
Mao, Haifang ;
Mao, Dongsen .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (07) :2605-2616
[10]   Ammonia Hydrothermally Treated SiO2 Supported Rh-Based Catalyst for CO Hydrogenation to C2 Oxygenates: Remarkable Effect of Support Pore Size [J].
Chen, Weimiao ;
Song, Xiangen ;
Ning, Lili ;
Ding, Yunjie .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (42) :18798-18807