Phosphorus Doping in Co9S8/Ni3S2 Hollow Nanorods for Supercapacitors

被引:1
作者
Cui, Shuangxing [1 ]
Wu, Lei [1 ]
Lu, Xintong [1 ]
Li, Guochang [1 ]
Xiao, Xunwen [2 ]
Han, Lei [1 ]
机构
[1] Ningbo Univ, Sch Mat Sci & Chem Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China
[2] Ningbo Univ Technol, Coll Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
supercapacitors; P doping; Co9S8/Ni3S2; surface reconstruction; hollow tube;
D O I
10.1021/acsanm.4c06617
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Metal sulfides, characterized by high crystalline stability and narrowed band gap, are recognized as effective electrode materials for energy storage in alkaline environments. This study enhances the surface activity in Co9S8/Ni3S2 hollow nanorod arrays by incorporating phosphorus (P) doping. In situ Raman spectroscopy confirms that P doping facilitates rapid surface reconstruction in alkaline media, resulting in substantial amounts of oxyhydroxides that significantly enhance the energy density of supercapacitors. The optimized P-Co9S8/Ni3S2 (1 h) electrode demonstrates a 4.56-fold increase in performance over the original Co9S8/Ni3S2, achieving a capacitance of 20.5 F<middle dot>cm(-2) at 3 mA<middle dot>cm(-2) in 2 M KOH. The hybrid supercapacitor device assembled with activated carbon achieves an energy density of 1.73 mWh cm(-2) at a power density of 4.95 mW cm(-2), showcasing a high cycling life with 84.6% capacity retention after 10,000 cycles. This work effectively reconstructs the activity of oxyhydroxide species on Co9S8/Ni3S2 electrodes in alkaline environments through P doping engineering, providing valuable guidance for the design of in situ reconstructions of metal sulfide electrodes using P atom doping engineering.
引用
收藏
页码:1617 / 1627
页数:11
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