Unveiling the impact of interphase properties on the modulus of composites reinforced with nanodiamond: Defining an interfacial adhesion parameter

被引：0
作者：
Nematollahi, Hadi [1 ]
Mohammadi, Mohsen [1 ]
Munir, Muhammad Tajammal [2 ]
Zare, Yasser [3 ]
Rhee, Kyong Yop [4 ]
Park, Soo-Jin [5 ]
机构：
[1] Qom Univ Technol, Fac Engn, Dept Polymer Engn, POB 37195-1519, Qom, Iran
[2] Amer Univ Middle East, Coll Engn & Technol, Egaila 54200, Kuwait
[3] ACECR, Motamed Canc Inst, Breast Canc Res Ctr, Biomat & Tissue Engn Res Grp,Dept Interdisciplinar, Tehran, Iran
[4] Kyung Hee Univ, Coll Engn, Dept Mech Engn BK21 Four, Yongin, South Korea
[5] Inha Univ, Dept Chem, Incheon 22212, South Korea
来源：
SURFACES AND INTERFACES | 2025年 / 59卷
关键词：
Nanodiamond-based composites; Young's modulus; Interfacial adhesion; Interphase; POLYMER NANOCOMPOSITES; CARBON NANOTUBES; TENSILE MODULUS; YIELD STRENGTH; PREDICTION; BEHAVIOR;
D O I：
10.1016/j.surfin.2025.105926
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this manuscript, Sato-Furukawa model is developed to predict the tensile modulus of nanodiamond (ND)- based samples, assuming the interfacial adhesion between ND and the matrix. Also, an unknown interfacial adhesion parameter (zeta) in Sato-Furukawa model is developed by interphase properties. The outcomes of the proposed model are compared with empirical data, and the level of precision is evaluated. Furthermore, it takes into account the size of the nanoparticles, which is an important factor that was not included in the original model. In summary, this research offers a quantitative analysis of zeta. Then, the impacts of various parameters such as interphase thickness (Ri), interphase modulus (Ei), ND radius (R), and filler concentration (phi f) on the modulus of the nanocomposite are investigated. The outcomes from the proposed model completely agree with the experimental findings of various samples. The results indicate a direct connection among the interphase characteristics and composite stiffness. Specifically, an interphase size of 10 nm and interphase modulus of 15 GPa at a ND concentration of phi f = 0.01 produce a 300 % improvement in the modulus of system. Moreover, the ideal combination of the smallest ND radius (2 nm) and the highest ND concentration (phi f = 0.04) results in a remarkable 250 % enhancement in the nanocomposite modulus.
引用
收藏
页数：10
相关论文
共 60 条
  • [1] Zhou Z., Wu Z., Liu H., Huang C., Wang T., Zhao Y., Miao Z., Xiang Y., Geng Z., He F., Enhancing cryogenic thermal conductivity of epoxy composites through the incorporation of boron nitride nanosheets/nanodiamond aerogels prepared by directional-freezing method, Polym. Compos, 45, pp. 2670-2684, (2024)
  • [2] Lin Y.-C., Perevedentseva E., Lin Z.-R., Chang C.-C., Chen H.-H., Yang S.-M., Lin M.-D., Karmenyan A., Speranza G., Minati L., Multimodal bioimaging using nanodiamond and gold hybrid nanoparticles, Sci. Rep, 12, (2022)
  • [3] Sedov V., Martyanov A., Ashkinazi E., Tiazhelov I., Savin S., Sovyk D., Mandal S., Fedorov S., Grigoriev S., Ralchenko V., Effect of diamond seeds size on the adhesion of CVD diamond coatings on WC-Co instrument, Surfac. Interfac., 38, (2023)
  • [4] Sturari S., Varzi V., Apra P., Britel A., Amine N.-H., Andrini G., Corte E., Tomagra G., Mino L., Olivero P., A comprehensive study of the effect of thermally induced surface terminations on nanodiamonds electrical properties, Surfac. Interfac., 38, (2023)
  • [5] Chen Q., Mao K.-L., Yao Y., Huang X.-H., Zhang Z., Nanodiamond/cellulose nanocrystals composite-based acoustic humidity sensor, Sensor. Actuator. B, 373, (2022)
  • [6] Ducrozet F., Girard H.A., Jianu T., Peulon S., Brun E., Sicard-Roselli C., Arnault J.-C., Unintentional formation of nitrate and nitrite ions during nanodiamonds sonication: a source of radical and electron scavengers, Colloid. Surfac. A, 663, (2023)
  • [7] Rehman A., Houshyar S., Wang X., Nanodiamond in composite: biomedical application, J. Biomed. Mater. Res. Part A, 108, pp. 906-922, (2020)
  • [8] Jabeen S., Kausar A., Muhammad B., Gul S., Farooq M., A review on polymeric nanocomposites of nanodiamond, carbon nanotube, and nanobifiller: structure, preparation and properties, Polym. Plast. Technol. Eng, 54, pp. 1379-1409, (2015)
  • [9] Kausar A., Nanodiamond reinforcement in polyamide and polyimide matrices: fundamentals and applications, J. Plastic Film Sheeting, 34, pp. 439-458, (2018)
  • [10] Pan F., Khan M., Tiehu L., Javed E., Hussain A., Zada A., Alei D., Wahab Z., Effect of nanodiamond particles on the structure, mechanical, and thermal properties of polymer embedded ND/PMMA composites, J. Polym. Eng., 42, pp. 795-807, (2022)
123456