An active self-healing and UV-resistant anticorrosion coating based on loading-enhanced nanocontainers tailored for Q235 carbon steel protection

被引:3
作者
Wang, Lin [1 ]
Zang, Jingyi [1 ]
Liu, Tong [1 ]
Sun, Fuyao [1 ]
Wang, Qiang [1 ]
Wang, Yin [1 ]
Zhang, Tiancai [2 ]
Xu, Jianhua [1 ]
Fu, Jiajun [1 ]
机构
[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China
[2] Southwest Inst Technol & Engn, Chongqing 400039, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
Corrosion protection; Triple effect; Controllable release; UV aging resistance; Epoxy coating; HEXAGONAL BORON-NITRIDE; MESOPOROUS SILICA NANOPARTICLES; CORROSION-INHIBITOR; COMPOSITE COATINGS; SURFACE-CHEMISTRY; MILD-STEEL; BENZOTRIAZOLE; POLYDOPAMINE; GRAPHENE; WATER;
D O I
10.1016/j.porgcoat.2025.109128
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Complex self-healing methods and limited UV resistance restrict the application of reactive organic protective coatings for intelligent corrosion-protection in harsh marine environments. To address this, ultra-high aspect ratio boron nitride nanosheets (BNNS) were developed for uniform growth of polydopamine (PDA), loaded with benzotriazole (BTA). These BNNS/PDA/BTA (BPB) nanocontainers achieved high BTA loading (168.4 mu g/mg) with efficient pH-sensitive release and excellent corrosion resistance (1.41 x 1010 Omega & sdot;cm2). After 30 days of immersion, the corrosion-rate of modified epoxy coatings was only 1.25 x 10-5 mm/year, and UV absorption of BPB maintained coating stability under prolonged exposure. This work informs heavy-duty anti-corrosion applications.
引用
收藏
页数:21
相关论文
共 134 条
[81]   Highly effective inhibition of mild steel corrosion in 3.5% NaCl solution by green Nettle leaves extract and synergistic effect of eco-friendly cerium nitrate additive: Experimental, MD simulation and QM investigations [J].
Ramezanzadeh, Mohammad ;
Sanaei, Zahra ;
Bahlakeh, Ghasem ;
Ramezanzadeh, Bahram .
JOURNAL OF MOLECULAR LIQUIDS, 2018, 256 :67-83
[82]   A comprehensive review on ultrathin, multi-functionalized, and smart graphene and graphene-based composite protective coatings [J].
Ren, Siming ;
Cui, Mingjun ;
Liu, Chengbao ;
Wang, Liping .
CORROSION SCIENCE, 2023, 212
[83]   Smart-release inhibition of corrosion driven organic coating failure on zinc by cationic benzotriazole based pigments [J].
Richards, C. A. J. ;
McMurray, H. N. ;
Williams, G. .
CORROSION SCIENCE, 2019, 154 :101-110
[84]   Mussel-inspired sulfonated polydopamine coating on anion exchange membrane for improving permselectivity and anti-fouling property [J].
Ruan, Huimin ;
Zheng, Zhihao ;
Pan, Jiefeng ;
Gao, Congjie ;
Van der Bruggen, B. ;
Shen, Jiangnan .
JOURNAL OF MEMBRANE SCIENCE, 2018, 550 :427-435
[85]   Self-repairing coatings containing active nanoreservoirs [J].
Shchukin, Dmitry G. ;
Moehwald, Helmuth .
SMALL, 2007, 3 (06) :926-943
[86]   Layer-by-layer assembled nanocontainers for self-healing corrosion protection [J].
Shchukin, Dmitry G. ;
Zheludkevich, Mikhail ;
Yasakau, Kiryl ;
Lamaka, Sviatlana ;
Ferreira, Mario G. S. ;
Moehwald, Helmuth .
ADVANCED MATERIALS, 2006, 18 (13) :1672-+
[87]   Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers [J].
Song, Li ;
Ci, Lijie ;
Lu, Hao ;
Sorokin, Pavel B. ;
Jin, Chuanhong ;
Ni, Jie ;
Kvashnin, Alexander G. ;
Kvashnin, Dmitry G. ;
Lou, Jun ;
Yakobson, Boris I. ;
Ajayan, Pulickel M. .
NANO LETTERS, 2010, 10 (08) :3209-3215
[88]   A Versatile Microporous Design toward Toughened yet Softened Self-Healing Materials [J].
Sun, Fuyao ;
Zhang, JingYi ;
Liu, Tong ;
Yao, Hai ;
Wang, Lin ;
Meng, HengYu ;
Gao, YunLong ;
Cao, YanFeng ;
Yao, BoWen ;
Xu, JianHua ;
Fu, JiaJun .
ADVANCED MATERIALS, 2024, 36 (50)
[89]   Hexagonal Boron Nitride/Polyaniline Nanocomposites for Anticorrosive Waterborne Epoxy Coatings [J].
Tang, Gongwen ;
Hou, Xiangyu ;
Wang, Yi ;
Yan, Zhishan ;
Ren, Tingting ;
Ma, Linrong ;
Huang, Xin ;
Wang, Chengpeng .
ACS APPLIED NANO MATERIALS, 2022, 5 (01) :361-372
[90]   Self-healing materials with microvascular networks [J].
Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, United States ;
不详 ;
不详 ;
不详 ;
不详 .
Nat. Mater., 2007, 8 (581-585) :581-585