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Synthesis of novel bioactive amides derived from carbazole moiety with deep-blue and single-component white photoluminescence
被引:0
|作者:
Ahmed, Mostafa
[1
]
Sayed, Mostafa
[1
]
Al-Hossainy, A. F.
[1
]
Tolba, Mahmoud S.
[1
]
Tsutsumi, Osamu
[2
]
Younis, Osama
[1
]
机构:
[1] New Valley Univ, Fac Sci, Chem Dept, El Kharga 72511, Egypt
[2] Ritsumeikan Univ, Coll Life Sci, Dept Appl Chem, Kusatsu 5258577, Japan
关键词:
Carbazole;
One-pot synthesis;
Single-component white emission;
Deep-blue luminescence;
Odd-even effect;
Biological activity;
LIGHT EMISSION;
DERIVATIVES;
HOST;
D O I:
10.1016/j.jphotochem.2025.116394
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
This work focuses on the chemical synthesis of three fluorescent bioactive amides tethered carbazole moiety by coupling 3-amino-9-ethylcarbazole with different aliphatic carboxylic acids including valeric, hexanoic, and heptanoic acids. NMR spectroscopy and HRMS were utilized to confirm the claimed structure of the target compounds indicating good agreement. The antimicrobial activity of fluorescent amides was assessed against different strains of gram negative and gram-negative bacterial as well as fungi demonstrating outstanding activity close or same as the control. Moreover, the molecular design, DFT calculations, and photoluminescence characteristics of these dyes have been investigated. The examined materials solutions emitted a deep-blue emission. Interestingly, with the powders, on the other hand, a single component emitted white light. The creation of aggregated molecules in the solid state improved the emission intensity at long visible wavelengths, resulting in a change in the emission color from the solution to the powder. The studied materials also emitted consistently at high temperatures. Furthermore, the odd-even effect both on the molecular packing and emission characteristics has been proven. As a result, the molecules under investigation provide a unique combination of benefits: a simple molecular structure, deep-blue emitters, white emission from a single material, and an odd-even effect.
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页数:12
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