In-Depth Study on Synergic Interactions and Thermo-Kinetic Analysis of (Wheat Straw and Woody Sawdust) Biomass Co-Pyrolysis over Mussel Shell-Derived CaO Catalyst Using Coats-Redfern Method

The behavior of wheat straw biomass (WS), woody sawdust biomass (WB), and their blends during catalytic co-pyrolysis are analyzed in the presence of CaO catalyst, which is obtained from the calcination of mussel shells. Synergy analysis of blends and pure materials is measured by studying the difference between theoretical and experimental values of wt.%/min, (RL%), and (WL%), which correspond to maximum weight loss rate, residue left, and weight loss, respectively. The Coats-Redfern method is utilized for evaluating the thermo-kinetic properties. The chemical reaction order model F1 is the best model that describes the Ea of 60.05 kJ/mol and triangle H, triangle G, and triangle S values of 55.03 kJ/mol, 162.26 kJ/mol, and -0.18 kJ/mol.K, respectively, for the optimum blend 80WS-20WB, reducing the thermo-kinetic properties. Model D3 showed better results for the Ea, triangle H, triangle G, and triangle S for the 5% CaO blend, which certified the viability of co-pyrolysis of WS and WB, while DTG indicated that exothermic and endothermic reactions occur together.