Molybdenum-Catalysed Deoxydehydration: Transforming Linear Aliphatic 1,2-Diols into Terminal Alkenes

被引：0

作者：

Peulecke, Normen ^{[1
]}

Sadeghi, Mahsa ^{[1
]}

Tin, Sergey ^{[1
]}

机构：

[1] Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2024年 / 366卷 / 23期

关键词：

Deoxydehydration; Molybdenum; Vicinal diol; Alkenes; Renewable resources; BIOMASS; CONVERSION; COMPLEXES; CHEMICALS; POLYOLS; DIOLS;

D O I：

10.1002/adsc.202400991

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Molybdenum catalysts bearing ONO, ON(N)O, ON(O)N and ON(S)O ligands were studied for catalytic deoxydehydration of vicinal diols. The complex bearing N ',N '-bis(2-hydroxy-3,5-dimethylbenzyl)-N,N-dimethylethylenediamine ligand afforded full conversion and up to 97% selectivities towards alkenes, when aliphatic vicinal diols were subjected to the reaction at 5 mol% catalyst loading.

引用

页码：4623 / 4626

页数：4

共 34 条

[31] Beyond Petrochemicals: The Renewable Chemicals Industry [J].

Vennestrom, P. N. R. ;

Osmundsen, C. M. ;

Christensen, C. H. ;

Taarning, Esben .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (45) :10502-10509

[32] Molybdenum catalysts based on salan ligands for the deoxydehydration reaction [J].

Wagner, Nathan J. ;

Tang, Wei-Chien ;

Wagner, Jonathan K. ;

Nguyen, Binh T. ;

Lam, Jamie Y. ;

Gibbons-Stovall, Skyler K. ;

Matias, Andrea C. ;

Martinez, Stephenie E. ;

Trieu-Tran, Tristhan ;

Clabaugh, Garrit M. ;

Navarro, Christine A. ;

Abboud, Ibrahim ;

Flores, Francis X. ;

Nicholas, Kenneth M. ;

John, Alex .

CATALYSIS SCIENCE & TECHNOLOGY, 2024, 14 (13) :3660-3673

[33]

Werpy T., 2004, Top Value Added Chemicals From Biomass: Vol. I-Results of Screening for Potential Candidates From Sugars and Synthesis Gas, DOE/GO-102004-1992

[34] Rhenium-catalyzed deoxydehydration of renewable triols derived from sugars [J].

Wozniak, Bartosz ;

Li, Yuehui ;

Tin, Sergey ;

de Vries, Johannes G. .

GREEN CHEMISTRY, 2018, 20 (19) :4433-4437

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