Molybdenum-Catalysed Deoxydehydration: Transforming Linear Aliphatic 1,2-Diols into Terminal Alkenes

被引：0

作者：

Peulecke, Normen ^{[1
]}

Sadeghi, Mahsa ^{[1
]}

Tin, Sergey ^{[1
]}

机构：

[1] Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2024年 / 366卷 / 23期

关键词：

Deoxydehydration; Molybdenum; Vicinal diol; Alkenes; Renewable resources; BIOMASS; CONVERSION; COMPLEXES; CHEMICALS; POLYOLS; DIOLS;

D O I：

10.1002/adsc.202400991

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Molybdenum catalysts bearing ONO, ON(N)O, ON(O)N and ON(S)O ligands were studied for catalytic deoxydehydration of vicinal diols. The complex bearing N ',N '-bis(2-hydroxy-3,5-dimethylbenzyl)-N,N-dimethylethylenediamine ligand afforded full conversion and up to 97% selectivities towards alkenes, when aliphatic vicinal diols were subjected to the reaction at 5 mol% catalyst loading.

引用

页码：4623 / 4626

页数：4

共 34 条

[1] Cellulose-based platform chemical: The path to application [J].

Artz, Jens ;

Palkovits, Regina .

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2018, 14 :14-18

[2] Bis(phenolato)molybdenum complexes as catalyst precursors for the deoxydehydration of biomass-derived polyols [J].

Beckerle, Klaus ;

Sauer, Andreas ;

Spaniol, Thomas P. ;

Okuda, Jun .

POLYHEDRON, 2016, 116 :105-110

[3] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[4] Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone [J].

Buntara, Teddy ;

Noel, Sebastien ;

Phua, Pim Huat ;

Melian-Cabrera, Ignacio ;

de Vries, Johannes G. ;

Heeres, Hero J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (31) :7083-7087

[5] Toward nonoxidative routes to oxygenated organics: Stereospecific deoxydehydration of diols and polyols to alkenes and allylic alcohols catalyzed by the metal oxo complex (C(5)Me(5))ReO3 [J].

Cook, GK ;

Andrews, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (39) :9448-9449

[6] Perspective on Overcoming Scale-Up Hurdles for the Reductive Catalytic Fractionation of Lignocellulose Biomass [J].

Cooreman, Elias ;

Vangeel, Thijs ;

Van Aelst, Korneel ;

Van Aelst, Joost ;

Lauwaert, Jeroen ;

Thybaut, Joris W. ;

Van den Bosch, Sander ;

Sels, Bert F. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (39) :17035-17045

[7] Molybdenum-Catalyzed Conversion of Diols and Biomass-Derived Polyols to Alkenes Using Isopropyl Alcohol as Reductant and Solvent [J].

Dethlefsen, Johannes R. ;

Lupp, Daniel ;

Teshome, Ayele ;

Nielsen, Lasse B. ;

Fristrup, Peter .

ACS CATALYSIS, 2015, 5 (06) :3638-3647

[8] Molybdenum-Catalyzed Deoxydehydration of Vicinal Diols [J].

Dethlefsen, Johannes R. ;

Lupp, Daniel ;

Oh, Byung-Chang ;

Fristrup, Peter .

CHEMSUSCHEM, 2014, 7 (02) :425-428

[9] Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals [J].

Deuss, Peter J. ;

Barta, Katalin ;

de Vries, Johannes G. .

CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (05) :1174-1196

[10] Recent Advances in the Deoxydehydration of Vicinal Diols and Polyols [J].

Donnelly, Liam J. ;

Thomas, Stephen P. ;

Love, Jason B. .

CHEMISTRY-AN ASIAN JOURNAL, 2019, 14 (21) :3782-3790

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