Silyl Radical-Participated Silylfunctionalization of Alkenes and Alkynes

被引：1
作者：
Zheng, Yang [1 ]
Zhu, Yi-Jie [1 ]
Zhang, Yi-Nan [1 ]
Chen, Fei [1 ]
机构：
[1] Anyang Normal Univ, Coll Chem & Chem Engn, Henan Prov Engn & Technol Res Ctr Precise Synth Fl, Henan Prov Key Lab New Optoelect Funct Mat, Anyang 455000, Henan, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 28卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Silyl radicals; Silylfunctionalization; Radical cascade reactions; Alkenes; Alkynes; SILANES; ARYLSILYLATION; SILYLARYLATION; ACTIVATION; ANNULATION; ACCESS;
D O I：
10.1002/ejoc.202401018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkenes and alkynes are inexpensive and readily available basic chemicals. Silyl radical-participated silylation of alkenes and alkynes provides a powerful tool for the direct construction of organosilicon compounds. Compared to hydrosilylation reactions, silylfunctionalization reactions are more attractive and advantageous in building diverse organosilicon compounds, which has led to their becoming a research focus in organic synthesis. Herein, we provide a comprehensive overview of recent advances in silyl radical-participated silylfunctionalization of alkenes and alkynes.
引用
收藏
页数：15
相关论文
共 56 条
  • [1] Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes
    Amrein, S
    Timmermann, A
    Studer, A
    [J]. ORGANIC LETTERS, 2001, 3 (15) : 2357 - 2360
  • [2] Brook M. A., 2000, Silicon in Organic, Organometallic, and Polymer Chemistry Silicon in Organic, Organometallic
  • [3] Visible light catalyzed arylsilylation of alkenes to construct silicon-containing 1,1-diaryl moieties
    Cao, Jia
    Gao, Liuzhou
    Wang, Guoqiang
    Li, Shuhua
    [J]. GREEN CHEMISTRY, 2024, 26 (08) : 4785 - 4791
  • [4] STRUCTURAL AND CHEMICAL-PROPERTIES OF SILYL RADICALS
    CHATGILIALOGLU, C
    [J]. CHEMICAL REVIEWS, 1995, 95 (05) : 1229 - 1251
  • [5] Copper-Catalyzed Radical Silylarylation of Activated Alkenes: Preparation of β-Silyl Amide-Pharmaceutical Hybrids
    Chen, Fei
    Liu, Shi-Yu
    Li, Xiao
    Jia, Jia-Lu
    Li, Yi
    Lu, Xiao-Lan
    Jia, Lin
    Zheng, Yang
    Yan, Zhongfei
    Li, Gang
    Lv, Yunhe
    Rong, Haojie
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2024, 366 (06) : 1325 - 1330
  • [6] Iron-Catalyzed Silylation and Spirocyclization of Biaryl-Ynones: A Radical Cascade Process toward Silylated Spiro[5.5]trienones
    Chen, Fei
    Zheng, Yang
    Yang, Hao
    Yang, Qing-Yun
    Wu, Lu-Yan
    Zhou, Nengneng
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (09) : 1537 - 1542
  • [7] Catalytic Silylation of Unactivated C-H Bonds
    Cheng, Chen
    Hartwig, John F.
    [J]. CHEMICAL REVIEWS, 2015, 115 (17) : 8946 - 8975
  • [8] Copper-Catalyzed Oxidative ipso-Annulation of Activated Alkynes with Silanes: An Approach to 3-Silyl Azaspiro[4,5]trienones
    Gao, Pin
    Zhang, Wanwan
    Zhang, Zhicheng
    [J]. ORGANIC LETTERS, 2016, 18 (22) : 5820 - 5823
  • [9] Iron-promoted free radical cascade difunctionalization of unsaturated benzamides with silanes
    Ge, Yaxin
    Tian, Yunfei
    Wu, Jilai
    Yan, Qinqin
    Zheng, Luping
    Ren, Yingming
    Zhao, Jincan
    Li, Zejiang
    [J]. CHEMICAL COMMUNICATIONS, 2020, 56 (83) : 12656 - 12659
  • [10] Visible-light-induced silylation: an update
    Ghosh, Sumit
    Lai, Dipti
    Hajra, Alakananda
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (11) : 2399 - 2415
123456